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Eric A Morrissey

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This dataset contains chemical and isotopic data from 39 produced water samples collected from sealed separators containing water from horizontal hydrocarbon wells in the lower Eagle Ford Group. The samples were collected from Lavaca and Gonzales counties, Texas in December, 2015. All wells had been in production for longer than 6 months and had produced more than 10,000 barrels (~160,000 liters) of water.
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Temporal and spatial sources of silica for chert remain poorly constrained. Modern sources to the worlds oceans include silica in rivers > aeolian (dust) deposition > sea floor vents and submarine weathering. However, changes in aridity and dust flux during the Phanerozoic may explain variations in the ocean silica cycle and times and places of chert formation. The chemistry of fine quartz dust (FQD) provides a chemical mechanism for the transformation of FQD to polymorphs of silica in chert; FQD is readily dissolved, then reprecipitated as Opal-A by either biotic or abiotic processes. An unequivocal relation between increases in dust flux and biogenic opal-A in the western Pacific Ocean during the past 200 kyr...
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The dataset consists of site identification, location, temperature and CO2 flux from diffuse emission measurement at the Tiptop fire. A total of 40 CO2 flux measurements were made at 27 locations, including five points (seven measurements) outside of the active coal fire area.
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To test if reflectance increases to sedimentary organic matter (vitrinite) caused by broad ion beam (BIB) milling were related to molecular aromatization and condensation, we used Raman and Fourier transform infrared (FTIR) spectroscopies to evaluate potential compositional changes in the same vitrinite locations pre- and post-BIB milling. The same locations also were examined by atomic force microscopy (AFM) to determine topographic changes caused by BIB milling (as expressed by the areal root-mean-square roughness parameter Rq). Samples consisted of four medium volatile bituminous coals. We used a non-aggressive BIB milling approach with conditions of [(5 min, 4 keV, 15°incline, 360° rotation at 25 rpm and 100%...
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Solid organic matter (OM) in sedimentary rocks produces petroleum and solid bitumen when it undergoes thermal maturation. The solid OM is a 'geomacromolecule', usually representing a mixture of various organisms with distinct biogenic origins, and can have high heterogeneity in composition. Programmed pyrolysis is a common conventional method to reveal bulk geochemical characteristics of the dominant OM while detailed organic petrography is required to reveal information about the biogenic origin of contributing macerals. Despite advantages of programmed pyrolysis, it cannot provide information about the heterogeneity of chemical compositions present in the individual OM types. Therefore, other analytical techniques...
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