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The biogeochemical cycling of sulfur (S) was studied during the 2000 snowmelt at Sleepers River Research Watershed in northeastern Vermont, USA using a hydrochemical and multi-isotope approach. The snowpack and 10 streams of varying size and land use were sampled for analysis of anions, dissolved organic carbon (DOC), 35 S activity, and δ 34 S and δ 18 O values of sulfate. At one of the streams, δ 18 O values of water also were measured. Apportionment of sulfur derived from atmospheric and mineral sources based on their distinct δ 34 S values was possible for 7 of the 10 streams. Although mineral S generally dominated, atmospheric-derived S contributions exceeded 50% in several of the streams at peak snowmelt and...
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Mechanisms underlying catchment export of nitrogen (N) during seasonal transitions (i.e., winter to spring and summer to autumn) were investigated in high-elevation catchments of the Sierra Nevada using stable isotopes of nitrate and water, intensive monitoring of stream chemistry and detailed catchment N-budgets. We had four objectives: (1) determine the relative contribution of snowpack and soil nitrate to the spring nitrate pulse, (2) look for evidence of biotic control of N losses at the catchment scale, (3) examine dissolved organic nitrogen ( DON) export patterns to gain a better understanding of the biological and hydrological controls on DON loss, and (4) examine the relationship between soil physico-chemical...
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The food webs of littoral, pelagic, and littoral-pelagic ecotone (interface) regions of a large subtropical lake were investigated using stable isotope ratio methods, expanding the focus of a previous fish-only study to include other food web components such as primary producers and invertebrates. In these food webs, delta13C increased approximately 4 per thousand and delta15N increased approximately 10 per thousand from primary producers to fish. The delta15N of fish was approximately 9 per thousand in the littoral zone, approximately 10 per thousand in the ecotone, and approximately 12 per thousand in the pelagic zone. The cross-habitat enrichment in fish 15N corresponded with both an increase in the size of fish...
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In the Rocky Mountains, there is uncertainty about the source areas and emission types that contribute to nitrate (NO3) deposition, which can adversely affect sensitive aquatic habitats of high-elevation watersheds. Regional patterns in NO3 deposition sources were evaluated using NO3 isotopes in five National Parks, including 37 lakes and 7 precipitation sites. Results indicate that lake NO3 ranged from detection limit to 38 μeq/L, δ18O (NO3) ranged from −5.7 to +21.3‰, and δ15N (NO3) ranged from −6.6 to +4.6‰. δ18O (NO3) in precipitation ranged from +71 to +78‰. δ15N (NO3) in precipitation and lakes overlap; however, δ15N (NO3) in precipitation is more depleted than δ15N (NO3) in lakes, ranging from −5.5 to −2.0‰....
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To determine whether NO 3 − concentration pulses in surface water in early spring snowmelt discharge are due to atmospheric NO 3 − , we analyzed stream δ 15 N-NO 3 − and δ 18 O-NO 3 − values between February and June of 2001 and 2002 and compared them to those of throughfall, bulk precipitation, snow, and groundwater. Stream total Al, DOC and Si concentrations were used to indicate preferential water flow through the forest floor, mineral soil, and ground water. The study was conducted in a 135-ha subcatchment of the Arbutus Watershed in the Huntington Wildlife Forest in the Adirondack Region of New York State, U.S.A. Stream discharge in 2001 increased from 0.6 before to 32.4 mm day −1 during snowmelt, and element...
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