In several countries biodiesel blending programs have been implemented looking for reduction in fossil fuel dependence and environmental benefits, including climate change mitigation. The current global biodiesel production, from different fatty raw materials, reaches about 6 billion liters per year and represents 10% of whole biofuel production. Nevertheless, in many cases the actual advantages of biodiesel production and usage are not clearly evaluated. Essentially, the feasibility of biodiesel production can be determined by its efficiency in solar energy conversion, as indicated by agro-industrial productivity and energy balance parameters, which expresses a relative demand of natural resources (land and energy) to produce biofuel. [...]