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Raman and Synchrotron X-ray Data of Sold Phases Used in Chromium Sequestration and Re-oxidation Experiments with Sand and Sediment from Hinkley, CA

Dates

Publication Date
Start Date
2015-01-22
End Date
2022-03-08

Citation

Foster, A.L., Wright, E.G., Bobb, C., Choy, D., and Miller, L.G., 2023, Optical Petrography, Bulk Chemistry, Micro-scale Mineralogy/Chemistry, and Bulk/Micron-Scale Solid-Phase Speciation of Natural and Synthetic Solid Phases Used in Chromium Sequestration and Re-oxidation Experiments with Sand and Sediment from Hinkley, CA: U.S. Geological Survey data release, https://doi.org/10.5066/P9ENBLGY.

Summary

This page contains (a) bulk synchrotron-based X-ray absorption spectra; (b) microbeam synchrotron-based X-ray fluorescence maps and spectra; and (c) microbeam Raman spectra (and corresponding optical images). These data were used to understand chromium, iron, and manganese valence and mineral residence in natural and synthetic mineral mixtures used in laboratory experiments designed to simulate dynamic conditions in an engineered aquifer system [see Izbicki and Groover (2018) and Miller and others (2020)].

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Attached Files

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MicroRaman_Spectra.zip 73.59 KB application/zip
Manganese_XANES.zip 142.98 KB application/zip
Iron_XANES_EXAFS.zip 39.78 KB application/zip
MicroRaman_Spectra_Information.csv 3.07 KB text/csv
MicroXRF_Map_Information.csv 504 Bytes text/csv
MicroXRF_Element_Maps.zip 365.93 KB application/zip
Guide_to_Data_in_Chapter_J.csv 8.4 KB text/csv
Chromium_XANES_EXAFS.zip 81.97 KB application/zip
Data_Dictionary_Raman_Synchrotron.csv 13.46 KB text/csv
MicroXRF_Element_Maps.zip 365.93 KB application/zip
MicroRaman_Optical_Images.zip 6.52 MB application/zip
XANES_EXAFS_Information.xlsx 22.03 KB application/vnd.openxmlformats-officedocument.spreadsheetml.sheet

Purpose

Synchrotron-based bulk and microbeam methods and data provide unique information on chromium oxidation state and mineral residence that is simply not possible to obtain by other methods. Similar information for iron and manganese is needed because these two elements form minerals that are known to be the most important hosts for chromium. Raman spectroscopy with micron-scale beams (e.g., microRaman) was used to identify the mineralogy of secondary coatings on mineral grains in natural or synthetic mineral mixtures used in the experiments described in in Miller and others (2020). Miller, L.G., Bobb, C., Bennett, S., and Baesman, S.M., 2020, Aqueous and Solid Phase Chemistry of Sequestration and Re-oxidation of Chromium in Experimental Microcosms with Sand and Sediment from Hinkley, CA: U.S. Geological Survey data release, https://doi.org/10.5066/P9U8C82V.

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Communities

  • USGS Data Release Products

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Provenance

Data source
Input directly
MicroRaman spectroscopic data were generated by the authors at USGS' laboratories in Menlo Park (CA). Synchrotron data were collected by Foster, Bobb, and Miller at the Stanford Synchrotron Laboratory (Menlo Park, CA) under proposal 4719. The data were input directly.

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