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18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well-instrumented research catchment in north-central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed-basin...
Reactive solute transport models are useful tools for analyzing complex geochemical behavior resulting from biodegradation of organic compounds by multiple terminal electron acceptors (TEAPs). The usual approach of simulating the reactions of multiple TEAPs by an irreversible Monod rate law was compared with simulations that assumed a partial local equilibrium or kinetically controlled reactions subject to the requirement that the Gibbs free energy of reaction (ΔG) was either less than zero or less than a threshold value. Simulations were performed using a single organic substrate and O2, FeOOH, SO4−2 and CO2 as the terminal electron acceptors. It was assumed that the organic substrate was slowly and completely...
The impact of agricultural chemicals on groundwater quality depends on the interactions of biogeochemical and hydrologic factors. To identify key processes affecting distribution of agricultural nitrate in groundwater, a parsimonious transport model was applied at 14 sites across the U.S. Simulated vertical profiles of NO3−, N2 from denitrification, O2, Cl−, and environmental tracers of groundwater age were matched to observations by adjusting the parameters for recharge rate, unsaturated zone travel time, fractions of N and Cl− inputs leached to groundwater, O2 reduction rate, O2 threshold for denitrification, and denitrification rate. Model results revealed important interactions among biogeochemical and physical...
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The U.S. Geological Survey (USGS) is providing an online map of stream and lake gage water level measurements on Long Island, New York, April-May 2013. USGS serves this map and geospatial data as a REST Open Map Service (as well as HTTP, JSON, KML, and shapefile), so end-users can use the map and data on mobile and web clients. A companion report, U.S. Geological Survey Scientific Investigations Map 3326 (Como and others, 2015; http://dx.doi.org/10.3133/sim3326) further describes data collection and map preparation and presents 68x22 in. PDF versions, 4 sheets, scale 1:125,000. Continuous records of water level altitude at 16 U.S. Geological Survey (USGS) streamgaging stations (15 streams and...
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NatureServe worked with several federal, state, and NGO partners in the United States and Mexico to conduct a climate change vulnerability assessment of major natural community types found within the Mojave and Sonoran Deserts. The project focused on ten major upland, riparian, and aquatic community types, including pinyon-juniper woodlands, Joshua tree-blackbrush scrub, creosote-bursage scrub, salt desert scrub, Paloverde-mixed cacti scrub, semi-desert grassland, desert riparian and stream, riparian mesquite bosque, and desert springs. This effort piloted a new Habitat Climate Change Vulnerability Index (HCCVI) approach being developed by NatureServe, as a companion to an existing index for species. The project...
Globally, bioremediation is a common choice for remediation of petroleum hydrocarbon-contaminated sites. For application at cold climate sites, bioremediation approaches are appealing because they have potential to be more efficient and cost-effective than alternative, more energy intensive approaches. Several bioremediation approaches have been reported to be successful for petroleum hydrocarbon-contaminated soils at cold climate sites. In contrast, there are relatively few publications on applications of bioremediation for petroleum-contaminated groundwater at cold climate sites. Most of the existing relevant groundwater studies were conducted at sites with either no permafrost, or with sporadic to discontinuous...
The permeability of continental crust is so highly variable that it is often considered to defy systematic characterization. However, despite this variability, some order has been gleaned from globally compiled data. What accounts for the apparent coherence of mean permeability in the continental crust (and permeability–depth relations) on a very large scale? Here we argue that large-scale crustal permeability adjusts to accommodate rates of internal and external forcing. In the deeper crust, internal forcing – fluxes induced by metamorphism, magmatism, and mantle degassing – is dominant, whereas in the shallow crust, external forcing – the vigor of the hydrologic cycle – is a primary control. Crustal petrologists...
The sources of nitrate (NO3−) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO3− concentrations in excess of the USEPA's drinking water standard of 10 mg N/l. Relative to background levels, the NO3− concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter...
Several studies have shown that the dominant streamflow generation mechanism in a river basin can leave distinct geomorphological signatures in basin topography. In particular, it has been suggested previously that basins generated by groundwater discharge tend to have a larger hypsometric integral than surface runoff basins because fluvial erosion is more focused in the valleys where groundwater discharge tends to occur. In this analysis, we aim to clarify this relationship by developing an alternative method to quantify the effects of streamflow generation mechanisms on basin hypsometry and by using a numerical model that can generate streamflow by different processes to evaluate the sensitivity of the results...
Denitrification was measured within a nitrate-contaminated aquifer on Cape Cod, Massachusetts, using natural gradient tracer tests with 15N nitrate. The aquifer contained zones of relatively high concentrations of nitrite (up to 77 μM) and nitrous oxide (up to 143 μM) and has been the site of previous studies examining ground water denitrification using the acetylene block technique. Small-scale (15–24 m travel distance) tracer tests were conducted by injecting 15N nitrate and bromide as tracers into a depth interval that contained nitrate, nitrite, nitrous oxide, and excess nitrogen gas. The timing of the bromide breakthrough curves at down-gradient wells matched peaks in 15N abundance above background for nitrate,...
Denitrification was measured within a nitrate-contaminated aquifer on Cape Cod, Massachusetts, using natural gradient tracer tests with 15N nitrate. The aquifer contained zones of relatively high concentrations of nitrite (up to 77 μM) and nitrous oxide (up to 143 μM) and has been the site of previous studies examining ground water denitrification using the acetylene block technique. Small-scale (15–24 m travel distance) tracer tests were conducted by injecting 15N nitrate and bromide as tracers into a depth interval that contained nitrate, nitrite, nitrous oxide, and excess nitrogen gas. The timing of the bromide breakthrough curves at down-gradient wells matched peaks in 15N abundance above background for nitrate,...
This study assessed the efficacy for removing Cryptosporidium parvum oocysts of poorly sorted, Fe- and Al-rich, subsurface sediments collected from 0.9 to 4.9 and 1.7–13.9 m below land surface at an operating riverbank filtration (RBF) site (Russian River, Sonoma County, CA). Both formaldehyde-killed oocysts and oocyst-sized (3 μm) microspheres were employed in sediment-packed flow-through and static columns. The degree of surface coverage of metal oxides on sediment grain surfaces correlated strongly with the degrees of oocyst and microsphere removals. In contrast, average grain size (D50) was not a good indicator of either microsphere or oocyst removal, suggesting that the primary mechanism of immobilization within...
Federally owned and managed public lands occupy approximately 30 percent of the land area of the United States, and anywhere from 50 percent to more than 80 percent of the land area of many of the western states. Determining the appropriate use of these lands involves balancing objectives related to economic, recreational, and conservation interests. This paper examines established and emerging conflicts within and across these objectives through both a narrative discussion of specific topics and a series of case studies. The authors find that new challenges, including pressures to devote portions of public lands to renewable energy project development and the multifaceted threats presented by climate change, will...
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The U.S. Geological Survey (USGS) is providing an online map of potentiometric-surface altitude contours in the Magothy and Jameco aquifers on Long Island, New York, April-May 2013. USGS serves this map and geospatial data as a REST Open Map Service (as well as HTTP, JSON, KML, and shapefile), so end-users can use the map and data on mobile and web clients. A companion report, U.S. Geological Survey Scientific Investigations Map 3326 (Como and others, 2015; http://dx.doi.org/10.3133/sim3326) further describes data collection and map preparation and presents 68x22 in. PDF versions, 4 sheets, scale 1:125,000. This polyline shapefile consists of digital contours that represent the potentiometric-surface...
Gradients in contaminant concentrations and isotopic compositions commonly are used to derive reaction parameters for natural attenuation in aquifers. Differences between field-scale (apparent) estimated reaction rates and isotopic fractionations and local-scale (intrinsic) effects are poorly understood for complex natural systems. For a heterogeneous alluvial fan aquifer, numerical models and field observations were used to study the effects of physical heterogeneity on reaction parameter estimates. Field measurements included major ions, age tracers, stable isotopes, and dissolved gases. Parameters were estimated for the O2 reduction rate, denitrification rate, O2 threshold for denitrification, and stable N isotope...
Shallow injection is the predominant mode of wastewater disposal for most tourist-oriented facilities and some residential communities in the US Florida Keys National Marine Sanctuary. Concern has been expressed that wastewater nutrients may be escaping from the saline groundwater system into canals and surrounding coastal waters and perhaps to the reef tract 10 km offshore, promoting unwanted algal growth and degradation of water quality. We performed a field study of the fate of wastewater-derived nitrate in the subsurface of a Florida Keys residential community (Key Colony Beach, FL) that uses this disposal method, analyzing samples from 21 monitoring wells and two canal sites. The results indicate that wastewater...
The satellite Gravity Recovery and Climate Experiment (GRACE) provides data describing monthly changes in the geoid, which are closely related to changes in vertically integrated terrestrial water storage. Unlike conventional point or gridded hydrologic measurements, such as those from rain gauges, stream gauges, rain radars, and radiometric satellite images, GRACE data are sets of Stokes coefficients in a truncated spherical harmonic expansion of the geoid. Swenson and Wahr [2002] describe techniques for constructing spatial averaging kernels, with which the average change in vertically integrated water storage within a given region can be extracted from a set of Stokes coefficients. This study extends that work...
Summary Freshwater storage in deep aquifers of Brooklyn and Queens, New York, USA, is under consideration as an emergency water supply for New York City. The purpose of a New York City storage and recovery system is to provide an emergency water supply during times of drought or other contingencies and would entail longer-term storage phases than a typical annual cycle. There is concern amongst neighboring coastal communities that such a system would adversely impact their local water supplies via increased saltwater intrusion. This analysis uses three-dimensional modeling of variable-density ground-water flow and salt transport to study conditions under which hypothetical aquifer storage and recovery (ASR) may...
18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well-instrumented research catchment in north-central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed-basin...
Groundwater ages estimated from environmental tracers can help calibrate groundwater flow models. Groundwater age represents a mixture of traveltimes, with the distribution of ages determined by the detailed structure of the flow field, which can be prone to significant transient variability. Effects of pumping on age distribution were assessed using direct age simulation in a hypothetical layered aquifer system. A steady state predevelopment age distribution was computed first. A well field was then introduced, and pumpage caused leakage into the confined aquifer of older water from an overlying confining unit. Large changes in simulated groundwater ages occurred in both the aquifer and the confining unit at high...
Categories: Publication; Types: Citation; Tags: age, groundwater, transient


map background search result map search result map Climate Change Vulnerability and Adaptation Strategies for Natural Communities Potentiometric Surface Contours of the Magothy and Jameco Aquifers, April-May 2013 Stream and Lake Average Water-Level Altitudes, April-May 2013 Stream and Lake Average Water-Level Altitudes, April-May 2013 Potentiometric Surface Contours of the Magothy and Jameco Aquifers, April-May 2013 Climate Change Vulnerability and Adaptation Strategies for Natural Communities