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This metadata record presents analytical results for laboratory microcosms conducted during 2016–18 as part of a study to develop a field test and numerical interpretation method to determine the effective diffusion coefficients and sorption coefficients of trichloroethene (TCE) and daughter products in the rock matrix of sedimentary rock, as well as biodegradation rate coefficients in the borehole. The biodegradation rate coefficients in the borehole are an important component of defining the back-diffusion of TCE from the matrix of sedimentary rock. Microcosm experiments were conducted with microbial community samples and groundwater collected from boreholes in the field test area to define anaerobic biodegradation...
The dataset consists of 30-year percentage depletion calculations, hydrocarbon group compositions, organic carbon mass fractions and hydrocarbon concentrations for 16 locations sampled at the Bemidji (MN) oil spill study site. Also included in the dataset are concentrations for 33 individual volatile hydrocarbons from the aforementioned sampling locations.
This version supersedes the previous version of this data release: Trost, J.J., Krall, A.L., Baedecker, M., Cozzarelli, I.M., Herkelrath, W.N., Jaeschke, J.B., and Bekins, B.A., 2018, Historical data sets including inorganic and organic chemistry of water, oil, and sediments, aquifer hydraulic conductivity, and sediment grain size distribution at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA, 1984-2010 (ver. 2.0, September 2019): U.S. Geological Survey data release, https://doi.org/10.5066/F7J101NV. This U.S. Geological Survey (USGS) Data Release provides data from samples and measurements completed at the National Crude Oil Spill Fate and Natural Attenuation...
Water resources around the world are contaminated with per- and polyfluoroalkyl substances (PFAS) due to releases from point sources on military installations, fire training centers, and chemical manufacturing sites. Non-point sources have also been identified including wastewater effluent, landfills, and biosolids application. PFAS are a major concern to myriad stakeholders as some are known to bioaccumulate, they have eco-toxicity effects, and they are highly recalcitrant. PFAS are often called “forever chemicals” due to their environmental persistence but many precursor PFAS are transformed in the environment by microbes. Recent work has shown that PFAS can be biologically degraded in laboratory studies, but...
Categories: Data;
Tags: Barnstable County,
Cape Cod,
DNA sequencing,
Environmental Health,
Hydrology,
In 2015-2018, the U.S. Geological Survey (USGS) in cooperation with the U.S. Environmental Protection Agency Great Lakes Restoration Initiative investigated the biodegradation of microcystins in source waters and sand filters from drinking-water plants in the Western Lake Erie Basin. Four source waters and three sand filtrate samples were collected from the intakes and sand filters of Lake Erie drinking-water plants and transported to the USGS Ohio Water Microbiology Laboratory, where investigators set up microcosms to enrich for and identify indigenous bacteria capable of degrading microcystins. Quality control samples were set up in the microcosms to check analyses and included positive controls, negative controls,...
Natural attenuation of organic contaminants in groundwater can give rise to a series of complex biogeochemical reactions that release secondary contaminants to groundwater. In a crude oil contaminated aquifer, biodegradation of petroleum hydrocarbons is coupled with the reduction of ferric iron (Fe(III)) hydroxides in aquifer sediments. As a result, naturally occurring arsenic (As), adsorbed to Fe(III) hydroxides in the aquifer sediment, is mobilized from sediment into groundwater. However, Fe(III) in sediment of other zones of the aquifer has the capacity to attenuate dissolved As via re-sorption. To better evaluate how long-term biodegradation coupled with Fe-reduction and As mobilization can redistribute As mass...
Categories: Data;
Tags: Bemidji, Beltrami County, Minnesota,
USGS Science Data Catalog (SDC),
arsenic,
biodegradation,
biogeochemical cycling,
This USGS data release includes all the data presented in peer-reviewed publication entitled "Degradation of MCHM (4-methylcyclohexanemethanol) in Sediments from Elk River, West Virginia". We conducted experiments on crude MCHM to examine photooxidation or biodegradation. We also assessed the potential of sediments to serve as a long-term source of MCHM and well as the potential for native microbial communities to catalyze the anaerobic breakdown of MCHM. We developed a quantitative method to measure the 2 isomers (cis- and trans-) of 4-MCHM, using solid phase micro-extraction (SPME), which had a minimum detection limit of 5 µg/L. The data release shows that the abiotic degradation experiments showed no evidence...
In a crude-oil-contaminated sandy aquifer at the Bemidji site in northern Minnesota, biodegradation of petroleum hydrocarbons has resulted in release of naturally occurring As to groundwater under Fe-reducing conditions. This data set was collected for a study that used chemical extractions of aquifer sediments collected in 1993 and 2011-2014 to evaluate the relationship between Fe and As in different redox zones (oxic, methanogenic, Fe-reducing, anoxic-sub-oxic transition) of the contaminated aquifer over a twenty year period. The data presented showed that 1) the aquifer has the capacity to naturally attenuate the plume of dissolved As, primarily through sorption; 2) Fe and As are linearly correlated in sediment...
Categories: Data;
Tags: USGS Science Data Catalog (SDC),
Water Quality,
arsenic,
biodegradation,
biogeochemical cycling,
This U.S. Geological Survey (USGS) Data Release provides concentrations from groundwater and soil extracts for iron (Fe), barium (Ba), strontium (Sr), cobalt (Co), and nickel (Ni). Groundwater analyses for pH and alkalinity are also included. Samples were collected at the National Crude Oil Spill Fate and Natural Attenuation Research Site, near Bemidji MN (USA) between 2009-2019. The site is in Beltrami County, where a high-pressure pipeline carrying crude oil burst in 1979 and spilled approximately 1.7 million liters (10,700 barrels) into glacial outwash deposits. A trace element plume occurred at the site, in which concentrations of Fe, Co, Ni, Ba, and Sr were mobilized from the sediments into the groundwater....
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