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A multiresidue method for solids (i.e., soil, sediment, sludge) was developed and evaluated for the analysis of pesticides and pesticide degradates. Initially, a well characterized soil was used to determine the recovery of target compounds using an Energized Dispersive Guided Extraction (EDGE) system with two extraction solvents, acetonitrile and 1:1 (v/v) hexane:acetone. Extracts were cleaned using solid-phase extraction (SPE) with graphitized carbon cartridges and three elution solvents, acetonitrile, dichloromethane, and 1:1 (v/v) dichlormethane:ethyl acetate. The individual SPE elutions from the two extraction solvents were analyzed separately via GC-MS/MS and LC-MS/MS for 210 pesticides and pesticide transformation...
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The detrimental effects of excess nutrients and sediment entering the Chesapeake Bay estuary from its watersheds have necessitated regulatory actions. Federally-mandated reductions are apportioned to bay jurisdictions based on the U.S. Environmental Protection Agency's Chesapeake Bay Time-Variable Watershed Model (CBPM). The Chesapeake Assessment Scenario Tool (CAST version CAST-19; cast.chesapeakebay.net; Chesapeake Bay Program, 2020) is a simplified, on-line version of the Phase 6 CBPM that simulates watershed nutrients delivery to the estuary using the original model's annual land-surface nutrient source and removal inputs and time-averaged climatological forecasting. Because it runs much faster than the CBPM,...


    map background search result map search result map CAST Data Input Disaggregation from County and Land-River Segment Scale to National Hydrography Dataset Plus, Version 1.1 Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy CAST Data Input Disaggregation from County and Land-River Segment Scale to National Hydrography Dataset Plus, Version 1.1