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Diel variations of concentrations of unfiltered and filtered total Hg and filtered methyl Hg were documented during 24-h sampling episodes in water from Silver Creek, which drains a historical gold-mining district near Helena, Montana, and the Madison River, which drains the geothermal system of Yellowstone National Park. The concentrations of filtered methyl Hg had relatively large diel variations (increases of 68 and 93% from morning minima) in both streams. Unfiltered and filtered (0.1-μm filtration) total Hg in Silver Creek had diel concentration increases of 24% and 7%, respectively. In the Madison River, concentrations of unfiltered and filtered total Hg did not change during the sampling period. The concentration...
1. We investigated diurnal nitrate (NO3−) concentration variability in the San Joaquin River using an in situ optical NO3− sensor and discrete sampling during a 5-day summer period characterized by high algal productivity. Dual NO3− isotopes (δ15NNO3 and δ18ONO3) and dissolved oxygen isotopes (δ18ODO) were measured over 2 days to assess NO3− sources and biogeochemical controls over diurnal time-scales.2. Concerted temporal patterns of dissolved oxygen (DO) concentrations and δ18ODO were consistent with photosynthesis, respiration and atmospheric O2 exchange, providing evidence of diurnal biological processes independent of river discharge.3. Surface water NO3− concentrations varied by up to 22% over a single diurnal...