Filters: Tags: Thermal Maturity (X) > partyWithName: Paul C Hackley (X)
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To test if reflectance increases to sedimentary organic matter (vitrinite) caused by broad ion beam (BIB) milling were related to molecular aromatization and condensation, we used Raman and Fourier transform infrared (FTIR) spectroscopies to evaluate potential compositional changes in the same vitrinite locations pre- and post-BIB milling. The same locations also were examined by atomic force microscopy (AFM) to determine topographic changes caused by BIB milling (as expressed by the areal root-mean-square roughness parameter Rq). Samples consisted of four medium volatile bituminous coals. We used a non-aggressive BIB milling approach with conditions of [(5 min, 4 keV, 15°incline, 360° rotation at 25 rpm and 100%...
Categories: Data;
Tags: Bituminous Coal,
Broad Ion Beam,
Coal resources,
Energy Resources,
Geochemistry,
Geological models for petroleum generation suggest thermal conversion of oil-prone sedimentary organic matter in the presence of water promotes increased liquid saturate yield, whereas absence of water causes formation of an aromatic, cross-linked solid bitumen residue. To test the influence of exchangeable hydrogen from water, organic-rich (22 wt.% total organic carbon, TOC) mudrock samples from the Eocene lacustrine Green River Mahogany zone oil shale were pyrolyzed under hydrous and anhydrous conditions at temperatures between 300 and 370°C for 72 hrs. Petrographic approaches including optical microscopy, reflectance, Raman spectroscopy, and scanning electron and transmission electron microscopy, supplemented...
Categories: Data;
Tags: Anhydrous pyrolysis,
Colorado,
Energy Resources,
Garfield County,
Geochemistry,
Recent production of light sweet oil from shallow (~2,000 ft) horizontal wells in the Upper Devonian Berea Sandstone of eastern Kentucky and historical oil production from conventional wells in the Berea of adjoining southern Ohio has prompted re-evaluation of Devonian petroleum systems in the central Appalachian Basin. Herein, we examined Upper Devonian Ohio Shale (lower Huron Member) and Middle Devonian Marcellus Shale organic-rich source rocks from eastern Ohio and nearby areas using organic petrography and geochemical analyses of solvent extracts. The data indicate the organic matter in the Ohio and Marcellus Shales was primarily derived from marine algae and its degradation products including bacterial biomass....
For sample mounting, organic petrology laboratories typically use cold-setting epoxy-resin (e.g., 40°C, used by Oklahoma Geological Survey, OGS) or heat-setting plastic (e.g., 180°C, used by U.S. Geological Survey, USGS). Previous workers have suggested a systematic vitrinite reflectance (VRo) increase was associated with the thermoplastic preparation process, relative to epoxy mounting, which was attributed to moisture loss from the transient high temperatures of plastic mounting. In this study, we evaluated thermal effects to low maturity organic matter from transient exposure to elevated temperatures. A subbituminous coal sample was subjected to long-term (4 to 38 weeks) exposure to temperatures of 85 to 120°C...
As part of a larger study, organic petrographic features of Leonardian Wolfcamp A repetitive siliceous and calcareous mudrock and fine-grained carbonate lithofacies cycles occurring in the R. Ricker #1 core from Reagan County, Midland Basin, Texas were evaluated. The objectives of the petrographic investigation were to estimate thermal maturity, identify organic matter types and abundances, and identify the presence or absence of migrated hydrocarbons. An integrated analytical program included geochemical screening [total organic carbon (TOC) content by LECO, programmed pyrolysis by HAWK, including from solvent-extracted samples], X-ray diffraction mineralogy, organic petrography, SEM-EDS including correlative light...
Categories: Data;
Tags: Energy Resources,
Organic petrography,
Reagan County,
Texas,
USGS Science Data Catalog (SDC),
The U.S. Geological Survey assessed undiscovered unconventional hydrocarbon resources reservoired in the Upper Cretaceous Tuscaloosa marine shale (TMS) of southern Mississippi and adjacent Louisiana in 2018. As part of the assessment, oil- source rock correlations were examined in the study area where operators produce light (38-45° API), sweet oil from horizontal, hydraulically-fractured wells in an overpressured ‘high-resistivity’ (>5 ohm-m) zone (HRZ) at the base of the TMS. Our initial characterization of TMS samples indicated overall low organic carbon (avg. TOC ~1.0%) and dominance of a gas-prone Type III or mixed Type II/III kerogen, potentially inconsistent with a self-sourced petroleum system model for...
Categories: Data;
Tags: Amite County,
Biomarkers,
East Feliciana County,
Energy Resources,
Franklin County,
Thirty-two organic-rich samples from the lower and upper shale members of the Devonian–Mississippian Bakken Formation were collected from eight cores across the Williston Basin, USA, at depths (~7,575–11,330 ft) representing immature through post peak oil/early condensate thermal maturity conditions. Reflectance results were correlated to programmed temperature pyrolysis parameters [hydrogen index (HI), production index (PI), Tmax], normal hydrocarbon and isoprenoid analysis of extractable organic matter (pristane/n-C17, phytane/n-C18) from GC analysis, and peak ratios from FTIR spectroscopy (branching ratio, A-factor).
Categories: Data;
Tags: Energy Resources,
Geochemistry,
North Dakota,
USGS Science Data Catalog (SDC),
geoscientificInformation,
Here the spatial variation in Raman estimates of thermal maturity within individual organic domains from several shale geologic reference materials originating from the Boquillas, Marcellus, Niobrara, and Woodford Formations are assessed from the respective Raman response. We show that for all four shales the thermal maturity parameters extracted from Raman spectra by iterative peak fitting can vary widely across distances of ≤5 µm within the same organic domain.
Categories: Data;
Tags: CEMEX quarry,
Carter County, Oklahoma,
Del Rio, Val Verde County, Texas,
Energy Resources,
Geochemistry,
This data release contains programmed pyrolysis, organic petrographic (reflectance), and semiquantitative X-ray diffraction mineralogy data for subsurface coal and shale samples from around the world. Samples were subjected to hydrous or anhydrous pyrolysis experiments at varying temperatures and the resulting residues were analyzed via programmed pyrolysis and reflectance to document changes in thermal maturity.
Raman spectroscopy was studied as a thermal maturity probe in a series of Upper Devonian Ohio Shale samples from the Appalachian Basin spanning from immature to dry gas conditions. Raman spectroscopy also was applied to samples spanning a similar thermal range created from 72-hour hydrous pyrolysis (HP) experiments of the Ohio Shale at temperatures from 300 to 360°C and isothermal HP experiments lasting up to 100 days of similar Devonian-Mississippian New Albany Shale. Raman spectra were treated by an automated evaluation software based on iterative and simultaneous modeling of signal and baseline functions to decrease subjectivity. Spectra show robust correlation to measured solid bitumen reflectance (BRo) values...
The U.S. Geological Survey assessed undiscovered petroleum resources in the downdip Paleogene formations of the U.S. Gulf Coast in 2018. During the assessment new data and information were collected to evaluate thermal maturity, source rock character, and unconventional reservoir rock prospectivity for the Cenozoic-aged section in south Louisiana. Samples were analyzed using multiple analytical approaches, including programmed pyrolysis (Rock-Eval), Leco TOC, organic petrographic analysis including vitrinite reflectance (Ro, %), and X-ray diffraction mineralogy. Associated abstract publication: Valentine, B.J., Elizalde, C., Enomoto, C.B., Hackley, P.C., 2015, Organic petrology and geochemistry of Tertiary and...
The molecular composition of petroliferous organic matter and its composition evolution throughout thermal advance are key to understanding and insight into petroleum generation. This information is critical for comprehending hydrocarbon resources in unconventional reservoirs, as source rock organic matter is highly dispersed, in contact with the surrounding mineral matrix, and may be present as multiple organic matter types. Here, a combination of Raman spectroscopy and optical microscopy approaches was applied to a marginally mature (vitrinite reflectance ~0.5%) sample of the Late Cretaceous Boquillas Shale before and after hydrous pyrolysis (HP) at 300 °C and 330 °C for 72 hours. This experimental design allowed...
Categories: Data;
Tags: Energy Resources,
Energy resources,
Hydrous pyrolysis,
Mudrock,
Organic matter,
This data release contains Rock-Eval pyrolysis, organic petrographic (reflectance), and X-ray diffraction mineralogy data for subsurface Mesozoic rock samples from the eastern onshore Gulf Coast Basin (primarily Mississippi and Louisiana). Samples were analyzed in support of the U.S. Geological Survey (USGS) assessment of undiscovered petroleum resources in the Upper Cretaceous Tuscaloosa marine shale and evaluation of shale gas prospectivity in the Aptian section of the Mississippi Salt Basin.
To test reproducibility of vitrinite and solid bitumen reflectance measurements in mudrocks, an interlaboratory study (ILS) was conducted using six samples from United States unconventional petroleum systems. Samples selected from the Marcellus, Haynesville, Eagle Ford, Barnett, Bakken and Woodford are representative of resource plays currently under exploitation in North America. All samples are from marine depositional environments, are thermally mature (Tmax >445°C) and have moderate to high organic matter content (2.9 to 11.6 wt.% TOC). The organic matter of the sample is dominated by solid bitumen, which contains intraparticle nano-porosity. Visual evaluation of organic nano-porosity via SEM suggests that intraparticle...
Categories: Data;
Tags: Bee County,
Billings County,
Energy Resources,
Harrison County,
Monongalia County,
This data release is a compilation of published and unpublished thermal maturity and source rock geochemical data (Rock-Eval, pyrolysis) from subsurface wells in the Permian Basin, west Texas and southeast New Mexico. These data include 67 newly collected samples and analyses from Delaware Basin wells (identified as Cicero_2022), as well as 1028 previously unpublished USGS analyses from the entire province (identified as LIMS). Data were also synthesized from publicly available sources, such as theses and dissertations, state agencies and databases, as well as from the body of published literature.
Categories: Data;
Tags: Central Basin Platform,
Delaware Basin,
Energy Resources,
Geochemistry,
Midland Basin,
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