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Natural water systems provide a wide range of conditions within which to examine the geochemical behavior and cycling of trace elements and nutrients relative to hydrochemically important mineral reactions. Processes of mineral dissolution, alteration and genesis exert strong controls on the concentrations of chemical species in natural water systems and thus on water quality. Chemical composition of atmospheric precipitation input to terrestrial watersheds affects mineral reaction rates and may regulate reaction pathways and products. Knowledge of the geochemical behavior and cycles of major elements, trace elements, and nutrients is essential in order to understand and predict the consequences of deliberate or...
Research objectives: i) To determine whether metals, including dissolved, colloidal and particulate metals, are bioavailable and toxic to organisms; ii) To characterize and parameterize the physiological and geochemical processes governing metal bioaccumulation, toxicity and ultimately trophic transfer in aquatic ecosystems. iii) To model metal bioaccumulation and toxicity using kinetic models iv) To develop approaches that use isotopically modified metals, metal nanoparticles and metal bound to distinct mineral phases (such as Cu on ferric oxides) to quantify their bioavailability and toxicity to organisms, in particular invertebrates; v) To use enriched metal isotopes to gain mechanistic understanding of...
The overall objective of this project is to determine the role of chemical processes associated with dissolved organic carbon (DOC) on the transport and reactivity of both naturally occurring and anthropogenic compounds. Defining the roles of DOC in environmental and geochemical processes is critical to understanding the nature and quality of the Nation’s water resources, and is important for future management of these resources. This field of study has increased in relevancy as numerous environmental problems have been linked to processes involving organic matter. My project attempts to meet these needs by focusing on the chemical mechanisms controlling the fate, transport, and reactivity of naturally occurring...
The overarching objective of my research is to integrate hydrology, pedology, chemistry, and physics to develop an improved process-level understanding of fluid, solute, and heat transport in unsaturated zones with applications ranging from geologic hazards to carbon storage in soils. I try to develop multi-disciplinary understanding of unsaturated zones in diverse settings with respect to groundwater-recharge and contaminant-transport determining processes, soil formation, and soil-water-plant-atmospheric interactions. I lead teams and work with others to generate individual and multidisciplinary synthesis products that address long-standing problems of fundamental importance to water resources, such as groundwater...
The determination of inorganic constituents and their impact on water quality requires an in-depth knowledge of the interactive water chemistry relationships. The ability to measure trace and ultratrace concentration levels of inorganic constituents as well as their chemical form and speciation plays a significant role on the chemical, toxicological, transport and overall environmental impact on surface- and ground-water hydrology. The development of state-of-the-art analytical chemistry technology to the solution of specific hydrologically related problems requires extensive laboratory and field research and development effort. Project objectives are to (1) Investigate and develop new concepts and approaches to...
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