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Concentrations of inorganic constituents, dissolved organic carbon (DOC), tritium, per- and polyfluoroalkyl substances (PFAS), volatile organic compounds (VOCs), and pharmaceuticals were measured in groundwater samples collected from 254 wells in 2019 and 2020. Concentrations of inorganic constituents, DOC, VOCs, and pharmaceuticals were measured at the U.S. Geological Survey (USGS) National Water Quality Laboratory in Lakewood, Colorado. Concentrations of tritium were measured at the USGS Tritium Laboratory in Menlo Park, California. Concentrations of PFAS were measured at SGS Laboratory in Orlando, Florida. In addition, several geospatial parameters were determined, including: percentages of selected land uses...
Data provided here describe geochemical correction of carbon-14 in dissolved inorganic carbon (DIC) for groundwater age dating. Datasets include major ion chemistry of groundwater samples, model parameter inputs, and final corrected carbon-14 in DIC. Geochemical correction was completed in two phases: determination of reactive phase mole transfers through an inverse geochemical model (PHREEQC; Parkhurst and Appleo, 1992) and tracking of isotopic mass transfer among phases (NetpathXL; Parkhusrtand Charlton, 2008). Parkhurst, D.L., and Appelo, C.A.J., 2013, Description of input and examples for PHREEQC version 3—A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical...
This data release documents nine Microsoft Excel tables that contain data for understanding groundwater ages in the Glacial aquifer system. Results for the three sample networks (PAS, principal aquifer study; MSS, modeling support study; FPS, flow path study) are described by three tables each: dissolved gas modeling results, environmental tracer concentrations (tritium, tritiogenic helium-3, sulfur hexafluoride, carbon-14, and radiogenic helium-4), and results for the mean age and age distribution. Tables are labeled by network and data type (as described below) separated by an underscore (_). For example, dissolved gas modeling results from the PAS network is label ‘PAS_NGmodel’. Dissolved gas modeling results...
This data release documents eight Microsoft Excel tables; four which contain data for understanding groundwater ages in the South East Coastal Plain (SECP), Coastal Lowlands (CLOW) and Mississippi Embayment and Texas Coastal Uplands (METX) aquifer systems and four that describe the data fields. Results described include dissolved gas modeling results, environmental tracer concentrations (tritium, tritiogenic helium-3, sulfur hexafluoride, and radiogenic helium-4), mean age and age distribution, and carbon-14 geochmical modeling results Dissolved gas modeling results (DGmodel) contains detailed information on the calibration of dissolved gas models to dissolved gas concentrations (neon, argon, krypton, xenon, and...
Continuous monitoring and discrete water-quality sampling were coupled in a karst aquifer to assess drivers and timescales of water-quality change. Water-quality data included environmental tracers of groundwater age (tritium [3H], tritiogenic helium-3 [3He-trit], sulfur hexafluoride [SF6], carbon-14 [14C], and radiogenic helium-4 [4He-rad]). All water quality data is available from the U.S. Geological Survey NWIS database (U.S. Geological Survey, 2019). Groundwater ages were estimated by calibration of environmental tracers to lumped parameter models of groundwater age for multiple samples collected at six groundwater wells using the program TracerLPM (Jurgens and others, 2012). The final estimates for mean groundwater...
This data release consists of data (in four tables) for assessing the time scales of arsenic variability in three production wells in New Hampshire; tables that describe the data fields in the data tables are also included in the data release. High-frequency (every 5 to 15 minutes) and bi-monthly water-quality monitoring of a bedrock-aquifer domestic well (425651070573701), a bedrock-aquifer public-supply well (425400070545401), and a glacial-aquifer public-supply well (425311070535801) was completed between 2014 and 2018. Concentrations of arsenic and other geochemical constituents and dissolved gases, as tracers of groundwater age, were measured on a bimonthly basis; physicochemical data, including specific conductance,...
Residence time distribution (RTD) is a critically important characteristic of groundwater flow systems; however, it cannot be measured directly. RTD can be inferred from tracer data with analytical models (few parameters) or with numerical models (many parameters). The second approach permits more variation in system properties but is used less frequently than the first because large-scale numerical models can be resource intensive. With the data and computer codes in this data release users can (1) reconstruct and run 115 General Simulation Models (GSMs) of groundwater flow, (2) calculate groundwater age metrics at selected GSM cells, (3) train a boosted regression tree model using the provided data, (4) predict...
Lithium concentrations in untreated groundwater from 1,464 public-supply wells, 1,676 domestic-supply wells, and 1,560 monitoring wells distributed across 33 principal aquifers in the United States were evaluated for spatial variations and possible explanatory factors. For context, lithium concentrations are compared to a drinking-water only threshold (60 micrograms per liter) and a Health-Based Screening Level (HBSL, 10 micrograms per liter). These thresholds were exceeded in 9% and 45% of samples from public-supply wells and in 6% and 37% from domestic-supply wells, respectively. Exceedances were most frequent for arid regions and older groundwater. Groundwater lithium concentrations were highest in unconsolidated...
Categories: Data;
Tags: Hydrology,
NAWQA,
USGS Science Data Catalog (SDC),
United States,
Water Quality,
Categorical classification of groundwater age based on concentrations of tritium (3H) in groundwater can provide useful information for the assessment and understanding of groundwater resources. These data present a three-part groundwater age classification system for the continental United States based on tritium thresholds that vary in space and time: modern (recharged after 1952), if the measured value is larger than an upper threshold; premodern (recharged prior to 1953) if the measured value is smaller than a lower threshold; or mixed if the measured value is between the two thresholds. Inclusion of spatially-varying that vary geographically on the basis of the location of the sample rather than a single threshold...
Groundwater age distribution and susceptibility to natural and anthropogenic contaminants were assessed for selected principal aquifers of the Western United States: the Central Valley aquifer system (CVAL), the Basin and Range basin-fill aquifers (BNRF), the Rio Grande aquifer system (RIOG), the High Plains aquifer (HPAQ), the Columbia Plateau basaltic-rock aquifers (CLPT), and the Colorado Plateaus aquifers (COPL). Groundwater ages were estimated by calibration of environmental tracers (tritium, tritiogenic helium-3, chlorofluorocarbons, sulfur hexafluoride, carbon-14 and radiogenic helium-4) to lumped parameter models (LPMs) for 1,353 samples from 1,182 sample locations. Groundwater samples were collected from...
Categories: Data;
Tags: Arizona,
Basin and Range Aquifers,
California,
Central Valley Aquifer,
Colorado,
Three wells in New Hampshire were sampled bimonthly over three years to evaluate the temporal variability of arsenic concentrations and groundwater age. All samples had measurable concentrations of arsenic throughout the entire sampling period and concentrations in individual wells varied, on average, by more than 7 µg/L. High arsenic concentrations (>10 µg/L) were measured in wells KFW-87 and SGW-93, consistent with the high pH and low dissolved oxygen typically found in bedrock wells. Lower arsenic concentrations (< 10 µg/L) at well SGW-65 were consistent with lower pH typical of the glacial aquifer. The well producing the oldest water, public bedrock well SGW-93, was not the well with the highest arsenic concentrations;...
Groundwater-quality data were collected from 559 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from January through December 2014. The data were collected from four types of well networks: principal aquifer study networks, which assess the quality of groundwater used for public water supply; land-use study networks, which assess land-use effects on shallow groundwater quality; major aquifer study networks, which assess the quality of groundwater used for domestic supply; and enhanced trends networks, which evaluate the time scales during which groundwater quality changes. Groundwater samples were analyzed for a large number of water-quality...
Categories: Data;
Types: Citation,
Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Hydrogeology,
NAWQA,
National Water Quality Program,
USGS Science Data Catalog (SDC),
United States,
Evaluating Decadal Changes in Groundwater Quality: Groundwater-quality data were collected from 5,000 wells between 1988-2001 (first decadal sampling event) by the National Water-Quality Assessment Project. Samples are collected in groups of 20-30 wells with similar characteristics called networks. About 1,500 of these wells in 67 networks were sampled again approximately 10 years later between 2002-2012 (second sampling event) to evaluate decadal changes in groundwater quality. Between 2012 and 2020 (third sampling event), a subset of these networks was sampled again, allowing additional results to be displayed on the web page: Decadal changes in groundwater quality (https://nawqatrends.wim.usgs.gov/decadal/)....
Ensemble-tree machine learning (ML) regression models can be prone to systematic bias: small values are overestimated and large values are underestimated. Additional bias can be introduced if the dependent variable is a transform of the original data. Six methods were evaluated for their ability to correct systematic and introduced bias: (1) empirical distribution matching (EDM); (2) regression of observed on estimated values (ROE); (3) linear transfer function (LTF); (4) linear equation based on Z-score transform (ZZ); (5) second machine learning model used to estimate residuals (ML2-RES); and (6) Duan smearing estimate applied after ROE is implemented (ROE-Duan). The performance of the methods was evaluated using...
Categories: Data;
Tags: Central Valley, California,
Glacial aquifer system,
Mississippi Embayment,
NAWQA,
North Atlantic Coastal Plain,
This data release includes grids representing the depth and thickness of drinking-water withdrawal zones, polygons of hydrogeologic settings, an inventory of sources of well construction data, and summaries of data comparisons used to assess the depth of groundwater used for drinking-water supplies in the United States. Well construction data sources are documented in Table1_DataSources.xlsx. Data comparisons using the Mann-Whitney test to assess similarity between hydrogeologic settings were used to justify combining data where they were sparse (compare_neighbors_all_domestic.txt and compare_neighbors_all_public.txt). Water-supply-well depth varies geographically by water use and the type of well, which illustrates...
Categories: Data,
Data Release - Revised;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Cycle 3,
Hydrology,
NAWQA,
USGS Science Data Catalog (SDC),
United States,
This dataset provides analytical and other data in support of an analysis of lead and manganese in untreated drinking water from Atlantic and Gulf Coastal Plain aquifers, eastern United States. The occurrence of dissolved lead and manganese in sampled groundwater, prior to its distribution or treatment, is related to the potential presence of source minerals and specific environmental factors including hydrologic position along the flow path, water-rock interactions, and associated geochemical conditions such as pH and dissolved oxygen (DO) concentrations. A DO/pH framework is proposed as a screening tool for evaluating risk of elevated lead or manganese, based on the occurrence of elevated lead and manganese concentrations...
Groundwater samples were collected from 60 public supply wells in the Colorado Plateaus principal aquifer. Water quality evaluations of groundwater for drinking water at public supply depths were made with the purpose of summarizing the current quality of source water (that is, untreated water) from public supply wells using two types of assessments; (1) status: an assessment that describes the current quality of the groundwater resource, and (2) understanding: an evaluation of the natural and human factors affecting the quality of groundwater, including an explanation of statistically significant associations between water quality and selected explanatory factors. To provide context for water-quality data, constituent...
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Arizona,
Colorado,
Cycle 3,
Hydrology,
NAWQA,
This data release includes tables and time-series plots of results for volatile organic compounds (VOCs) analyzed in samples of groundwater used for public supply that were collected by the USGS National Water-Quality Assessment (NAWQA) Project and the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) during 2013-19; results for associated quality-control samples also are included. All samples were analyzed by the USGS National Water Quality Laboratory (NWQL) using laboratory schedules 4436 and 4437. The table of groundwater data includes VOC results as reported by the laboratory, along with results that represent the application...
The location of a point (or pixel) within the conterminous U.S. can be assigned based on its position relative to the Nation’s stream network. Two metrics are recognized: lateral position (LP) and distance from stream to divide (DSD). And given that a point can have different positions in different hydrologic orders the term multi-order hydrologic position (MOHP) is used to describe the ensemble of hydrologic positions. LP and DSD were developed for nine hydrologic orders across the conterminous U.S. (Belitz and others, 2019; Moore and others, 2019). Four case studies are presented here that were used for evaluating the utility of MOHP in the context of random forest machine learning (Belitz and others, 2019)....
Categories: Data;
Tags: Central Valley, California,
Conterminous United States,
Cycle 3,
Fox-Wolf-Peshtigo,
Groundwater,
Chemical data from 43,334 wells were used to examine the role of land surface-soil-aquifer connections in producing elevated manganese concentrations (>300 µg/L) in United States (U.S.) groundwater. Elevated manganese and dissolved organic carbon (DOC) concentrations were associated with shallow water tables and organic-carbon rich soils, suggesting soil-derived DOC supported manganese reduction. Manganese and DOC concentrations were higher near rivers than farther from rivers, suggesting river-derived DOC also supported manganese reduction. Anthropogenic nitrogen may also affect manganese concentrations in groundwater. In parts of the northeastern U.S. containing poorly buffered soils, ~40% of the samples with...
Categories: Data;
Tags: Environmental Health,
Hydrogeology,
NAWQA,
National Water Quality Program,
USGS Science Data Catalog (SDC),
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