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Arsenic compounds have been used extensively in agriculture in the US for applications ranging from cotton herbicides to animal feed supplements. Roxarsone (3-nitro-4-hydroxyphenylarsonic acid), in particular, is used widely in poultry production to control coccidial intestinal parasites. It is excreted unchanged in the manure and introduced into the environment when litter is applied to farmland as fertilizer. Although the toxicity of roxarsone is less than that of inorganic arsenic, roxarsone can degrade, biotically and abiotically, to produce more toxic inorganic forms of arsenic, such as arsenite and arsenate. Experiments were conducted on aqueous litter leachates to test the stability of roxarsone under different...
The effects of a dry-rewetting event (D/RW) on soil microbial properties and nutrient release by leaching from two soils taken from adjacent grasslands with different histories of management intensity were studied. These were a low-productivity grassland, with no history of fertilizer application and a high-productivity grassland with a history of high fertilizer application, referred to as unimproved and improved grassland, respectively. The use of phospholipid fatty acid analysis (PLFA) revealed that the soil of the unimproved grassland had a significantly greater microbial biomass, and a greater abundance of fungi relative to bacteria than did the improved grassland. Soils from both grasslands were maintained...
Arsenic compounds have been used extensively in agriculture in the US for applications ranging from cotton herbicides to animal feed supplements. Roxarsone (3-nitro-4-hydroxyphenylarsonic acid), in particular, is used widely in poultry production to control coccidial intestinal parasites. It is excreted unchanged in the manure and introduced into the environment when litter is applied to farmland as fertilizer. Although the toxicity of roxarsone is less than that of inorganic arsenic, roxarsone can degrade, biotically and abiotically, to produce more toxic inorganic forms of arsenic, such as arsenite and arsenate. Experiments were conducted on aqueous litter leachates to test the stability of roxarsone under different...