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The molecular composition of petroliferous organic matter and its composition evolution throughout thermal advance are key to understanding and insight into petroleum generation. This information is critical for comprehending hydrocarbon resources in unconventional reservoirs, as source rock organic matter is highly dispersed, in contact with the surrounding mineral matrix, and may be present as multiple organic matter types. Here, a combination of Raman spectroscopy and optical microscopy approaches was applied to a marginally mature (vitrinite reflectance ~0.5%) sample of the Late Cretaceous Boquillas Shale before and after hydrous pyrolysis (HP) at 300 °C and 330 °C for 72 hours. This experimental design allowed...
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To test reproducibility of vitrinite and solid bitumen reflectance measurements in mudrocks, an interlaboratory study (ILS) was conducted using six samples from United States unconventional petroleum systems. Samples selected from the Marcellus, Haynesville, Eagle Ford, Barnett, Bakken and Woodford are representative of resource plays currently under exploitation in North America. All samples are from marine depositional environments, are thermally mature (Tmax >445°C) and have moderate to high organic matter content (2.9 to 11.6 wt.% TOC). The organic matter of the sample is dominated by solid bitumen, which contains intraparticle nano-porosity. Visual evaluation of organic nano-porosity via SEM suggests that intraparticle...


    map background search result map search result map Testing reproducibility of vitrinite and solid bitumen reflectance measurements in North American unconventional petroleum systems (2019) Reflectance, Raman band separation and Mean multivariant curve resolution (MCR) in organic matter in Boquillas Shale Reflectance, Raman band separation and Mean multivariant curve resolution (MCR) in organic matter in Boquillas Shale Testing reproducibility of vitrinite and solid bitumen reflectance measurements in North American unconventional petroleum systems (2019)