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Fitzpatrick, John

The spatial and temporal changes in hydrology and pore water elemental and 87Sr/86Sr compositions are used to determine contemporary weathering rates in a 65- to 226-kyr-old soil chronosequence formed from granitic sediments deposited on marine terraces along coastal California. Soil moisture, tension and saturation exhibit large seasonal variations in shallow soils in response to a Mediterranean climate. These climate effects are dampened in underlying argillic horizons that progressively developed in older soils, and reached steady-state conditions in unsaturated horizons extending to depths in excess of 15 m. Hydraulic fluxes (qh), based on Cl mass balances, vary from 0.06 to 0.22 m yr−1, resulting in fluid residence...
Categories: Publication; Types: Citation
The spatial and temporal changes in hydrology and pore water elemental and 87Sr/86Sr compositions are used to determine contemporary weathering rates in a 65- to 226-kyr-old soil chronosequence formed from granitic sediments deposited on marine terraces along coastal California. Soil moisture, tension and saturation exhibit large seasonal variations in shallow soils in response to a Mediterranean climate. These climate effects are dampened in underlying argillic horizons that progressively developed in older soils, and reached steady-state conditions in unsaturated horizons extending to depths in excess of 15 m. Hydraulic fluxes (qh), based on Cl mass balances, vary from 0.06 to 0.22 m yr−1, resulting in fluid residence...
Categories: Publication; Types: Citation
A comprehensive geochemical survey of springs outside the northwest margin of the Yellowstone caldera was undertaken in 2003 and 2004. This survey was designed to detect: (1) active leakage from a huge reservoir of CO2 gas recently postulated to extend from beneath the caldera into this area; and (2) lingering evidence for subsurface flow of magmatic fluids into this area during the 1985 seismic swarm and concomitant caldera subsidence. Spring temperatures are low (< 15 °C), but two large-discharge springs contain 14C-dead carbon that can be identified as magmatic from calculated end-member values for δ13C(dead) and 3He/C(dead) of − 4‰ and 1 × 10− 10, respectively, similar to values for intra-caldera fumarolic and...
Concentrations of CO2 in soil atmosphere and CO2 efflux were measured across a marine terrace soil chronosequence near Santa Cruz, California. Soil development, specifically the formation of an argillic horizon, has created a two-tier soil gas profile in the older terrace soils. The soil above the argillic horizon has seasonal variations in soil CO2 associated with plant respiration. The older soils with dense argillic horizons maintain a year round ∼1%CO2 below the argillic horizon. The CO2efflux during the growing season is higher on the older terraces.
Categories: Publication; Types: Citation
Concentrations of CO2 in soil atmosphere and CO2 efflux were measured across a marine terrace soil chronosequence near Santa Cruz, California. Soil development, specifically the formation of an argillic horizon, has created a two-tier soil gas profile in the older terrace soils. The soil above the argillic horizon has seasonal variations in soil CO2 associated with plant respiration. The older soils with dense argillic horizons maintain a year round ∼1%CO2 below the argillic horizon. The CO2efflux during the growing season is higher on the older terraces.
Categories: Publication; Types: Citation
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