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Monique Adams

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Inorganic compositions of flowback and co-produced waters from hydrocarbon extraction have been studied directly and through laboratory experiments that seek to replicate subsurface water-rock interaction. Here a broad analysis is made of compositions from the U.S. Geological Survey Produced Waters Database (v2.3) and leachates (water, hydrochloric acid, artificial brine) for 12 energy-resource related shales from across the United States. The database illustrates common ranges for 26 elements in 4 produced water types and enhanced solubility with increasing ionic strength is observed for Al, Ba, Fe, Li, Mn, Rb, Sr, and possibly 11 other elements. Differences are observed between laboratory leachates and produced...
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Smelter slag containing copper and other trace elements is widespread in riverbed sediment of the upper Columbia River (UCR) of the United States. To evaluate potential risk to aquatic life concentrations of copper and other trace elements were measured in shallow pore-water and in river water samples collected near the sediment-water interface. Samples were collected using an in-situ pore-water profiler to collect a suite of four water samples from above, at, and below the sediment-water interface at each of 29 sampling locations; pore-water collected with a drive-point sampler at 10 additional locations; and Stabilized Liquid Membrane Device samplers (SLMDs) to allow determination of trace-element concentrations...
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Samples were collected at or near baseflow conditions. Water pH and specific conductance were measured in the field, with specific conductance also measured in the laboratory and calculated based on the ionic strength of samples based on laboratory analyses. Water samples were collected for laboratory analyses using a peristaltic pump with silicon tubing. Samples were filtered through a reusable plexiglass filter holder with nylon screws using 0.45µm polyethersulfone membranes that were rinsed with approximately 20mL of sample water prior to collection. Splits were also collected unfiltered to determine trace metal concentrations associated with suspended sediments. The filtration apparatus was rinsed with deionized...
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