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The U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board collected produced water samples for analysis of volatile organic compounds (VOCs) in the eight California oil fields of Fruitvale, Lost Hills, North Belridge, Orcutt, Placerita, South Belridge, Midway-Sunset, and Buena Vista from 2016 to 2020. Sampled sites included oil wells; injectate from tanks, pipelines, and injection wells where produced water from many wells, after removal of oil, is stored or transported prior to underground injection; integrated produced water from many oil wells collected from pipelines before oil removal; and surface disposal ponds where produced water, after removal of oil, is disposed...
The Bemidji crude oil spill site is a long-term USGS study site to understand the fate of crude oil in the shallow subsurface. A description of the site can be found at https://mn.water.usgs.gov/projects/bemidji. In 2014 concentrations of non-volatile dissolved organic carbon (NVDOC) were three times higher than diesel range organics (DRO) in the contaminant plume*. This is important because most of the NVDOC in the plume is composed of partial transformation products of compounds from the crude oil that are not reflected in a DRO analysis. In 2016 we conducted a campaign to determine if DRO values continue to reflect only a fraction of the NVDOC. These data are the results of that campaign. A total of 25 wells...
Categories: Data;
Tags: USGS Science Data Catalog (SDC)
The dataset consists of 30-year percentage depletion calculations, hydrocarbon group compositions, organic carbon mass fractions and hydrocarbon concentrations for 16 locations sampled at the Bemidji (MN) oil spill study site. Also included in the dataset are concentrations for 33 individual volatile hydrocarbons from the aforementioned sampling locations.
This version supersedes the previous version of this data release: Trost, J.J., Krall, A.L., Baedecker, M., Cozzarelli, I.M., Herkelrath, W.N., Jaeschke, J.B., and Bekins, B.A., 2018, Historical data sets including inorganic and organic chemistry of water, oil, and sediments, aquifer hydraulic conductivity, and sediment grain size distribution at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA, 1984-2010 (ver. 2.0, September 2019): U.S. Geological Survey data release, https://doi.org/10.5066/F7J101NV. This U.S. Geological Survey (USGS) Data Release provides data from samples and measurements completed at the National Crude Oil Spill Fate and Natural Attenuation...
These metadata sets present the comprehensive geochemical composition of solid and water samples from the site of a 11.4ML (million liters) wastewater spill discovered in January, 2015. Analyses of a pipeline sample (analyses of select analytes), supplied by the North Dakota Department of Health are also included. The spill was near Blacktail Creek, north of Williston, ND. The leak was from a pipeline located approximately 70m from Blacktail Creek. The creek flows 17km before entering the Little Muddy River, a tributary to the Missouri River. The study included samples collected in waters upstream and downstream from Blacktail Creek in February and June 2015, June 2016, and June 2017. These data sets include field...
The U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board collected produced water and gas samples in the Midway-Sunset, Poso Creek, and Buena Vista Oil Fields in Kern County in 2020 and 2021. Sampled sites included oil wells; injectate from tanks, pipelines, and injection wells where produced water from many wells, after removal of oil, is stored or transported prior to underground injection; and integrated produced water from many oil wells collected from pipelines before oil removal. This digital dataset contains the site information, analyzing laboratories and methods, and water and gas chemistry and quality-control results for these samples. Chemistry results include...
The data presented includes chloride concentration and specific conductance in surface water collected from 33 wetlands in the Williston Basin of Montana and North Dakota, 2015-2017 as well as count data for three species of amphibians captured at each wetland. Data also includes concentrations of metals in bed sediment and larval amphibians collected from 32 and 12 wetlands, respectively in 2015-2016. Abundance of barred tiger salamanders (Ambystoma mavortium), boreal chorus frogs (Pseudacris maculata), northern leopard frogs (Lithobates pipiens) was estimated at 33 wetlands from 2015-2017. Surface water was collected in the summer from each wetland in 2015-2017 at the same time as the amphibian surveys and analyzed...
In a crude-oil-contaminated sandy aquifer at the Bemidji site in northern Minnesota, biodegradation of petroleum hydrocarbons resulted in transient increases in magnetic susceptibility under high water table conditions. The magnetic susceptibility subsequently decreased again when the water table dropped. This data set was assembled to illustrate the cause of the magnetic susceptibility changes. These data show that alkalinity is high and dissolved oxygen is low in the area where the increased magnetic susceptibility is found. The decrease in the magnetic susceptibility can be attributed to the long term decline in sediment Fe(III) concentrations with time. The decrease is caused by iron reducing bacteria converting...
Categories: Data;
Tags: Bemidji,
Pinewood,
USGS Science Data Catalog (SDC),
dissolved metals,
groundwater quality,
Note: this version has been superseded by version 3.0: Trost, J.J., Krall, A.L., Baedecker, M., Cozzarelli, I.M., Herkelrath, W.N., Jaeschke, J.B., Delin, G.N., Berg, A.M., and Bekins, B.A., 2020, Data Sets from the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA (ver. 3.0, March 2020): U.S. Geological Survey data release, https://doi.org/10.5066/P9FJ8I0P. This U.S. Geological Survey (USGS) Data Release provides analytical data from samples and measurements completed at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota (Site) between 1984 and 2010. Included are inorganic and organic chemistry data from water, oil, and...
The Marcellus Shale Energy and Environment Laboratory (MSEEL) site is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The wells were completed in December 2015. Large volumes of wastewater are generated with natural gas production. These wastewaters contain organic and inorganic chemical constituents from fracturing fluids used during drilling and stimulation of gas in host rocks/shale, as well as chemical compounds that are derived from...
This U.S. Geological Survey (USGS) Data Release is focused on the geochemistry of wastewater (including flowback and produced water) samples, co-produced with natural gas, collected from the Marcellus Shale Energy and Environment Laboratory (MSEEL) site. MSEEL is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The wells were completed in December 2015. Large volumes of wastewater are generated with natural gas production. These wastewaters...
In crude-oil-contaminant plumes the dissolved organic carbon (DOC) is mainly hydrocarbon degradation intermediates only partly quantified by the diesel range total petroleum hydrocarbon (TPHd) method. To understand potential biological effects of degradation intermediates we tested three fractions of DOC: (1) solid phase extract (HLB); (2) dichloromethane (DCM-total) extract used in TPHd; and (3) DCM extract with hydrocarbons isolated by silica gel cleanup (DCM-SGC). Bioactivity of extracts from five wells spanning a range of DOC was tested using an in vitro multiplex reporter system that evaluates modulation of activity of 46 transcription factors; extracts were evaluated at concentrations equivalent to the well...
Data supporting "Common hydraulic fracturing fluid additives alter the structure and function of anaerobic microbial communities", describing iron reduction experiments, microbial community profiling, and statistical testing of data.
Categories: Data;
Tags: Aquatic Biology,
Ecology,
Energy Resources,
Environmental Health,
Fayette County,
Oil and gas (OG) wastewaters are commonly disposed of by underground injection and previous research showed that activities at a disposal facility in West Virginia affected stream biogeochemistry and sediment microbial communities downstream from the facility. Microorganisms can control the fate and transport of organic and inorganic components of OG wastewater highlighting the need to characterize the effects of OG wastewater components on microbial activity. We conducted a series of aerobic microcosm experiments to assess the influence of high total dissolved solids (TDS) and hydraulic fracturing fluid additives (2,2-dibromo-3-nitrilopropionamide (DBNPA), a biocide, and ethylene glycol, an anti-scaling additive),...
Categories: Data;
Tags: Biochemistry,
DNA sequencing,
Energy Resources,
Environmental Health,
Fayette County,
The Permian Basin, straddling New Mexico and Texas, is one of the most productive oil and gas (OG) provinces in the United States. OG production yields large volumes of wastewater that contain elevated concentrations of major ions including salts (also referred to as brines), and trace organic and inorganic constituents. These OG wastewaters pose unknown environmental health risks, particularly in the case of accidental or intentional releases. Releases of OG wastewaters have resulted in water-quality and environmental health effects at sites in West Virginia (Akob, et al., 2016, Orem et al. 2017, Kassotis et al. 2016) and in the Williston Basin region in Montana and North Dakota (Cozzarelli et al. 2017, Cozzarelli...
Management of petroleum-impacted waters by monitored natural attenuation (MNA) requires an understanding of the toxicology of both the original compounds released as well as the transformation products formed during natural breakdown. Here, we report data from a groundwater plume consisting of a mixture of crude oil compounds and transformation products resulting from a crude-oil release in August, 1979 near Bemidji, MN, USA. Water samples were characterized for activation of 52 human nuclear receptor (NR) activities and 50 transcriptional pathways associated with toxic responses. Five replicate analyses were performed for each solution at strengths of 1, 3, and 10 times the sample concentration. Radar plots of...
Categories: Data;
Tags: Bemidji,
Pinewood,
USGS Science Data Catalog (SDC),
Water Quality,
groundwater quality,
The Marcellus Shale Energy and Environment Laboratory (MSEEL) is part of the Northeast Natural Energy LLC (NNE) production facility on the Monongahela River in Monongalia County, West Virginia, USA. Natural gas extraction in the area creates large volumes of wastewater that may contain chemical compounds that pose risks to humans, animals, and the environment. The U. S. Geological Survey (USGS) has been studying the organic compounds in water produced from shale gas wells and in 2014, NNE started drilling two production wells in the Marcellus Shale. The well, MIP (Morgantown Industrial Park) -5H, was completed the following year. Samples were collected from this well. Large volumes of wastewater fluids were produced...
These analyses provide the basic geochemical composition of urban stormwater runoff from rainwater/stormwater that does or has the potential to infiltrate groundwater from Green Infrastructure control measures. These measures are able to mimic the natural landscape with engineered designed systems to enhance stormwater infiltration to groundwater.
Categories: Data;
Tags: Geochemistry,
USGS Science Data Catalog (SDC),
Water Quality,
alkalinity,
anions,
This U.S. Geological Survey (USGS) Data Release is focused on the geochemistry of wells within the oil zone and groundwater monitoring wells away from the oiled zone at the National Crude Oil Spill Fate and Natural Attenuation Research Site, Bemidji MN (USA) from 1985-2015. The site located in Beltrami County is where a high-pressure pipeline carrying crude oil burst in 1979 and spilled approximately 1.7 million liters (10,700 barrels) of crude oil into glacial outwash deposits. Researchers and scientists from government agencies, academic institutions, the regulatory community, and private companies have conducted extensive investigations of groundwater geochemistry in hopes of understanding the evolution of plumes...
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