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Germanium (Ge) is an increasingly important element used in critical technologies for communication, defense, and computing. However, Ge is scarce, and there is no United States (U.S.) primary production. Additionally, the environmental behavior of Ge is poorly understood. Germanium does not generally form its own minerals, but is instead recovered as a byproduct of zinc mining or of coal fly ash. It has been deemed critical by the U.S. and globally, and investigations of its geologic concentration, environmental fate and transport, and potential for recovery are crucial for maintaining a sustainable supply. A relevant study site to explore questions of environmental behavior and the potential to recover...
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Germanium (Ge) is an element deemed critical globally, and used in electronics, communication, and defense applications. The supply of Ge is limited and as demand for it increases, its criticality increases. Germanium is exclusively recovered as a byproduct of either coal mining or zinc (Zn) mining, and the main mineral hosting Ge in Zn deposits is sphalerite (ZnS). However, the mechanisms of Ge enrichment in sphalerite during mineral deposit formation are poorly understood. Therefore, investigations on the mechanisms controlling geologic enrichment of Ge in ores is crucial for maintaining a sustainable supply. For this study, we used a combination of techniques including optical and electron microscopy, synchrotron-based...
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Electron microprobe analyses of sphalerite (ZnS) and hemimorphite (Zn4Si2O7(OH)2·H2O) from sampled historical waste piles were conducted with a specific focus on germanium (Ge). In mine wastes at the Tar Creek Superfund Site, Oklahoma, USA, Ge is associated with ZnS (sphalerite) as expected, but weathering in the waste piles has led to a significant amount of Ge being incorporated into a zinc-silicate, hemimorphite. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical...
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Oxidation state and bonding environment of Ge and Cu in ZnS and Zn mineral concentrates from a variety of sources [Central Tennessee mining district (TN), Metaline mining district, (WA), and Red Dog mine (AK)] were determined by linear combination fits from x-ray absorption spectroscopy (XAS) analysis. Sphalerites from the East Tennessee mining district contained Ge in concentrations that were too low to generate a X-ray absorption spectra with an edge step. When applicable, Ge content in quartz was determined using XAS edge steps. Data and methods reported are part of a research study published in the 'Related External Resources' section below.
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Mineral abundances within bulk and size-fractionated mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S.A., were determined by Mineral Liberation Analysis (MLA) and X-Ray Diffraction (XRD). Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical minerals, Applied Geochemistry, p. 105341, https://doi.org/10.1016/j.apgeochem.2022.105341
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Elemental concentrations for bulk and size-fractionated mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S. were determined after dissolution via acid digests or a sodium peroxide fusion. Elemental concentrations were determined for the leachate from a simulated rainwater leach of mine wastes. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical mineral
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These worksheets contain data from geochemical analyses of solid mill tailings and other ore processing materials from worldwide localities, and leachates from those samples.
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Oxidation state and bonding environment of Ge in minerals within mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S. were determined by linear combination fits from x-ray absorption near edge spectroscopy (XANES) analysis. Ge content in quartz within these wastes was determined using XANES edge steps, and Ge content in sphalerite was compared using XANES edge steps versus electron microprobe analyses. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility...
Electron microprobe analyses of sphalerite (ZnS) were collected on samples from current or past mining operations in the USA with a specific focus on germanium (Ge), a byproduct critical mineral recovered from sphalerite. Data and methods reported are part of a research study published in the 'Related External Resources' section below.


    map background search result map search result map Elemental concentrations for bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Solid and aqueous geochemistry for mill tailings and other ore processing materials Electron microprobe analyses of sphalerite and hemimorphite from mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Geochemical, mineralogical, and molecular scale speciation characterization of mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Molecular speciation of Ge within sphalerite, hemimorphite, and quartz from mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Mineral abundances within bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Electron microprobe analyses of sphalerite from Central and East Tennessee mining districts, the Red Dog mining district (AK), and the Metaline mining district (WA) Molecular-scale speciation of germanium and copper within sphalerite from Central Tennessee mining district (TN), Red Dog mining district (AK), and Metaline mining district (WA) Trace element composition and molecular-scale speciation characterization of sphalerite from Central and East Tennessee mining districts, Red Dog mining district (AK), and Metaline mining district (WA) Elemental concentrations for bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Electron microprobe analyses of sphalerite and hemimorphite from mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Mineral abundances within bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Molecular speciation of Ge within sphalerite, hemimorphite, and quartz from mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Geochemical, mineralogical, and molecular scale speciation characterization of mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Electron microprobe analyses of sphalerite from Central and East Tennessee mining districts, the Red Dog mining district (AK), and the Metaline mining district (WA) Molecular-scale speciation of germanium and copper within sphalerite from Central Tennessee mining district (TN), Red Dog mining district (AK), and Metaline mining district (WA) Trace element composition and molecular-scale speciation characterization of sphalerite from Central and East Tennessee mining districts, Red Dog mining district (AK), and Metaline mining district (WA) Solid and aqueous geochemistry for mill tailings and other ore processing materials