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Neonicotinoids have become the most widely used insecticides in world with rapid growth in applications as seed coatings. Nontarget organisms are exposed to concentrated levels of pesticidal active ingredients through ingestion of treated seeds. To better understand pesticide fate, analytical methods are necessary to rapidly screen and accurately quantitate contaminants in environmental and biological matrices. Liquid chromatography-tandem mass spectrometry (LC-MS/MS) is commonly employed for neonicotinoid analyses but requires expensive analytical instrumentation and potentially laborious sample preparation. Enzyme-linked immunosorbent assays (ELISAs) are efficient and sensitive alternative methods for neonicotinoid...
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Irrigation runoff and soil samples were collected from a lettuce field located at the USDA-ARS Spence Research farm in the Salinas Valley, California to measure neonicotinoid insecticides (clothianidin and imidacloprid) and a fungicide (azoxystrobin) applied via coated seed and drench treatments. The field trial was designed to evaluate four treatments with replication: 1) control, untreated seed, 2) imidacloprid treated seed, 3) clothianidin treated seed, and 4) azoxystrobin treated seed with an imidacloprid drench. Samples were collected from each treatment over two lettuce growing seasons: August to October 2019 and September to October 2020. Runoff samples were collected over both growing seasons during 6 irrigation...
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Here we report optical data collected as part of a collaborative study between USGS Pennsylvania Water Science Center, Pennsylvania Department of Environmental Protection and Water Mission Area Proxies Project. The optical measurements reported here were collected to aide in the characterization of water sources and mixtures and establish proxies (surrogates) for per- and poly-fluorinated alkyl substances within the Neshaminy Creek basin. Data are compiled into three tables: 1) full fluorescence spectra in vectorized format, 2) full absorbance spectra, and 3) summary file of commonly extracted optical indicators and field-based sensor arrays.
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Nitrapyrin is a nitrification inhibitor that is co-applied with N-fertilizer in agroecosystems. Over the course of one year (March 2016 to June 2017), 192 water samples from seven streams across Iowa and Illinois were analyzed for nitrapyrin, its degradate 6-chloropicolinic acid (6-CPA), and three widely used herbicides acetochlor, atrazine, and metolachlor. Additional environmental samples were collected and analyzed in spring 2017: 63 water samples from eight subsurface drains, and 33 soil samples from a field in Iowa that received direct application of nitrapyrin (only for nitrapyrin and herbicides). Nitrapyrin was detected in all seven streams (56% detection) with concentrations ranging from 4 to 1,200 ng/L;...
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A multiresidue method for solids (i.e., soil, sediment, sludge) was developed and evaluated for the analysis of pesticides and pesticide degradates. Initially, a well characterized soil was used to determine the recovery of target compounds using an Energized Dispersive Guided Extraction (EDGE) system with two extraction solvents, acetonitrile and 1:1 (v/v) hexane:acetone. Extracts were cleaned using solid-phase extraction (SPE) with graphitized carbon cartridges and three elution solvents, acetonitrile, dichloromethane, and 1:1 (v/v) dichlormethane:ethyl acetate. The individual SPE elutions from the two extraction solvents were analyzed separately via GC-MS/MS and LC-MS/MS for 210 pesticides and pesticide transformation...
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Four dichloroacetamide herbicide safeners (AD-67, benoxacor, dichlormid, and furilazole) and two co-applied herbicides (acetochlor and metolachlor) were measured in water samples from 7 streams across Iowa and Illinois. Iowa water samples were collected from March 2016 to June 2017, and Illinois water samples were collected from September 2016 to June 2017. The compounds studied are applied to corn, and Iowa and Illinois are the two largest corn producing states in the U.S. The seven stream sites are all adjacent to agricultural fields in corn production. Water samples (1-L) were collected in amber glass bottles using a grab or depth weighted approach. With the exception of one site, Iowa River at Wapello (USGS...
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Nitrapyrin, a nitrification inhibitor, 6-CPA, a nitrapyrin degradate, and three co-applied herbicides (acetochlor, atrazine, and metolachlor) were measured in surface drains from eights sites in Illinois. Water samples were collected from April to June 2017. The compounds studied are applied to corn, Illinois is one of the largest corn producing states in the U.S. Water samples (1-L) were collected in amber glass bottles using a grab or depth weighted approach. Water samples were filtered (0.7 micrometers), extracted via solid phase extraction (Oasis® MAX cartridge), and analyzed (nitrapyrin and herbicides by gas chromatography with mass-spectrometry; 6-CPA by liquid chromatography tandem mass-spectrometry).
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Nitrapyrin, a nitrification inhibitor, 6-CPA, a nitrapyrin degradate, and three co-applied herbicides (acetochlor, atrazine, and metolachlor) were measured in water samples from seven streams across Iowa and Illinois. Iowa water samples were collected from March 2016 to June 2017, and Illinois water samples were collected from September 2016 to June 2017. The compounds studied are applied to corn, and Iowa and Illinois are the two largest corn producing states in the U.S. The seven stream sites are all adjacent to agricultural fields in corn production. Water samples (1-L) were collected in amber glass bottles using a grab or depth weighted approach. With the exception of one site, Iowa River at Wapello (USGS Site...
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Nitrapyrin, a nitrification inhibitor, and three co-applied herbicides (acetochlor, atrazine, and metolachlor) were measured in soil samples from an agricultural field in Iowa. Samples were collected from three locations in the field before and after nitrapyrin application in April-May 2017. Soils were collected using a 5-inch pipe that was hammered into the ground. Soil samples were extracted using pressurized solvent extraction (with dichloromethane), clean-up via solid phase extraction (carbon and alumina sorbents), and analyzed by gas chromatography with mass-spectrometry.


    map background search result map search result map Herbicide Safener and Co-Applied Herbicide Concentrations for Seven Streams across Iowa and Illinois (March 2016 to June 2017) Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US Nitrapyrin, 6-CPA, and herbicide concentrations in streams in the Midwestern US (March 2016 to June 2017) Nitrapyrin, 6-CPA, and herbicide concentrations in subsurface drains in the Midwestern US (April 2017 to June 2017) Nitrapyrin and herbicide concentrations in soil in the Midwestern US (April 2017 to May 2017) Insecticide and fungicide concentrations in irrigation runoff and soils from a lettuce field in the Salinas Valley, California, 2019 and 2020 Evaluation of ELISA for the Analysis of Imidacloprid in Plasma, Liver, and Fecal Matter Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy Optical measurements for surface water samples collected within the Neshaminy Creek basin during November 2021 Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive extraction with analysis by gas and liquid chromatography tandem mass spectroscopy Insecticide and fungicide concentrations in irrigation runoff and soils from a lettuce field in the Salinas Valley, California, 2019 and 2020 Optical measurements for surface water samples collected within the Neshaminy Creek basin during November 2021 Nitrapyrin and herbicide concentrations in soil in the Midwestern US (April 2017 to May 2017) Nitrapyrin, 6-CPA, and herbicide concentrations in subsurface drains in the Midwestern US (April 2017 to June 2017) Herbicide Safener and Co-Applied Herbicide Concentrations for Seven Streams across Iowa and Illinois (March 2016 to June 2017) Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US Nitrapyrin, 6-CPA, and herbicide concentrations in streams in the Midwestern US (March 2016 to June 2017) Evaluation of ELISA for the Analysis of Imidacloprid in Plasma, Liver, and Fecal Matter