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Slug additions are often the most accurate method for determining discharge when traditional current meter or acoustic measurements are unreliable because of high turbulence, rocky streambed, shallow or sheet flow, or the stream is physically inaccessible (e.g., under ice or canyon walls) or unsafe to wade (Zellweger et al., 1989, Kilpatrick and Cobb 1984, Ferranti 2015). The slug addition method for determining discharge requires an injection of a known amount of a single salt and high-frequency downstream measurement of solute concentration to capture the response curve (Kilpatrick and Cobb 1984). A new slug method was developed to determine stream discharge utilizing specific conductance and ionic molal conductivities...
Categories: Data;
Tags: Geochemistry,
Hydrology,
NA,
USGS Science Data Catalog (SDC),
Water Quality,
Sediment cores were collected in the Cache Creek Settling Basin (CCSB), Yolo County, California, during October 2011 at 10 locations (borehole sites) and during August 2012 at 5 other locations. Total core depths ranged from approximately 4.6 to 13.7 meters (15 to 45 feet), with penetration to about 9.1 meters (30 feet) at most locations. Detailed subsampling (3-centimeter intervals) was done at total of seven locations: six along an east-west transect in the southern part of the Cache Creek Settling Basin and at one in the northern part of the basin for analyses of total mercury; organic content; and cesium-137, which was used for dating. This data release reports results of the analyses of each subsample of these...
Atmospheric deposition of reactive nitrogen (Nr) can impact the soil microbial community structure and function and thus ecosystem processing and export of nutrients. Ecosystem response to atmospheric inputs of nitrogen depends on several factors, including elevational climate conditions (freeze/thaw cycles, precipitation), geology, soil and vegetation type, N speciation and microbial community structure. The focus of this study was to evaluate how spatial and seasonal variations in N deposition affect the ability of soil microbial communities to process N along an elevational gradient (1700 to 3015 meters) from plains to subalpine ecosystems west of Boulder, Colorado. In conjunction with a study measuring the variability...
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Ecology,
Environmental Health,
Geochemistry,
Land Use Change,
Soil Sciences,
Atmospheric deposition of reactive nitrogen (Nr) due to human activities can have measurable effects on ecosystem processing and export of nutrients, groundwater and surface-water quality. Rates of Nr deposition to lower-elevation forests immediately adjacent to the Denver/Boulder urban area, however, have only recently been measured. The focus of this study was to determine the extent of urban and agricultural N pollution transport to the Colorado Front Range. In conjunction with the Network for Urban Atmospheric Nitrogen Chemistry (NUANC) and the National Atmospheric Deposition Program (NADP), we measured wet-plus-dry Nr deposition and evaluated spatial and seasonal variations in N deposition along an elevational...
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Colorado,
Ecology,
Environmental Health,
Geochemistry,
Land Use Change,
In support of paleoclimatology investigations, samples of mammillary calcite, calcitic folia, and flowstone were collected by the U.S. Geological Survey in Devils Hole and Devils Hole Cave 2, Nevada, between 1983 and 1996. These samples came from about 60 m below to 9 m above the modern water table in these caverns. To determine δ18O and δ13C time series spanning the interval 567.7–4.5 ka, more than a thousand samples were milled and analyzed for their δ18O and δ13C values. To determine time-series ages, more than a hundred samples were analyzed using uranium-series dating. Many of these measurement results have not been published. Herein, we provide previously unpublished δ13C and δ18O values, and we provide unpublished...
Categories: Data;
Tags: Death Valley National Park,
Devils Hole,
Devils Hole Cave 2,
USGS Science Data Catalog (SDC),
carbon,
This product consists of one tabular dataset and associated metadata of water quality information related to rivers, streams, and reservoirs in the Upper Mississippi River watershed between 2012 and 2016. This data release is a part of a national assessment of freshwater aquatic carbon fluxes. Data consist of organic and inorganic carbon related species, carbon dioxide and methane gas fluxes calculated from manual chamber measurements, nitrogen species, carbon isotopes, oxygen isotopes, cations, anions, trace metals, and various in situ measurements including: pH, water temperature, air temperature, barometric pressure, dissolved oxygen, turbidity, fluorescent dissolved organic matter, and specific conductance....
Categories: Data,
Project;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Carbon,
Fluorescent Dissolved Organic Matter (fDOM),
Minnesota,
Shingobee,
Shingobee Headwaters Aquatic Ecosystems Project,
This dataset is in support of the publication "The addition of 144Nd to routine ICP-MS analysis as a quick screening tool for approximating earth elements (Q-STAR) in natural waters". It contains inductively coupled plasma mass spectrometry (ICP-MS) data from samples analyzed at the National Water Quality Laboratory (NWQL) from April 2021-May 2022. Data listed include estimated neodymium (Nd) concentrations and site numbers.Site numbers can be used to search published USGS data bases such as the National Water Information System, NWIS for previously published sample information and is shown here to highlight unpublished estimated Nd concentrations from this work. A set of archived samples from NWQL analyses were...
This dataset provides the expected and determined concentrations of selected inorganic and organic analytes for spiked reagent-water samples (calibration standards and limit of quantitation standards) that were used to calculate detection limits by using the United States Environmental Protection Agency’s (USEPA) Method Detection Limit (MDL) version 1.11 or 2.0 procedures, ASTM International’s Within-Laboratory Critical Level standard procedure D7783-13, and, for five pharmaceutical compounds, by USEPA’s Lowest Concentration Minimum Reporting Level procedure. Also provided are determined concentration data for reagent-water laboratory blank samples, classified as either instrument blank or set blank samples, and...
Categories: Data;
Tags: USGS Science Data Catalog (SDC),
Water Quality,
blank sample,
calibration standard,
chemical analysis,
This dataset contains measurements of dissolved hydrocarbons in from groundwater samples collected in the shale gas producing regions of West Virginia, USA, between June and August of 2018. The target analytes in this study were: methane (CH4), ethane (C2H6), ethene (C2H4), ethyne (C2H2), propane (C3H8), propene (C3H6), i-butane (C4H10), n-butane (C4H10), 1-butene (C4H8), propyne (C3H4), i-pentane (C5H12), n-pentane (C5H12), 2-methyl-pentane (C6H14), 3-methyl-pentane (C6H14), hexane (C6H14), and benzene (C6H6). This dataset also contains corresponding measurements of chlorofluorocarbons (CFCs), Sulfurhexafluoride (SF6), dissolved permanent gases (N2/Ar), tritium, the isotope ratio of helium dissolved in water, the...
Categories: Data;
Tags: Energy Resources,
Environmental Health,
Geochemistry,
USGS Science Data Catalog (SDC),
USGS-EMA-LOW-SS Oil and gas,
Rio Tinto, Spain, is an example of a fluvial system strongly influenced by acid rock and acid mine drainage. During the spring of 2018 and 2019, samples of stream waters and mine waters, biofilms, sediments and rocks, were collected in the field by Aubrey Zerkle. These samples were analyzed for comprehensive geochemistry, including Cr isotope geochemistry, anions and cations. Mineralogical analysis was conducted on powdered sediments and rocks.
Categories: Data;
Tags: Geochemistry,
Rio Tinto,
Spain,
USGS Science Data Catalog (SDC),
acid mine drainage,
The USGS National Field Manual (NFM) states “A representative sample is one that typifies in time and space that part of the aqueous system to be studied” and “obtaining representative samples is of primary importance for a relevant description of the environment.” The NFM contains detailed chapters on the best practices for representative and contamination free sampling of major and trace metals (U.S. Geological Survey 2006). However, as analytical capabilities have advanced and new preservation methods developed, there is a need to study the effectiveness of various amounts of nitric acid preservation for trace metals and major cations in surface water and groundwater. The amount of nitric acid prescribed by...
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Geochemistry,
USGS Science Data Catalog (SDC),
Water Quality,
biota,
water quality
Surface water, springs and wells in Pinnacles National Park (San Benito and Monterey Counties, CA) were sampled in the Fall of 2016 and Spring of 2017. Field parameters such as in situ pH, TDS/conductivity, and temperature were assessed. GPS coordinates for all samples were taken. Comprehensive groundwater chemistry, including major and minor elements, alkalinity, nutrients (and other parameters), Sr isotopes and REE concentrations, was analyzed at the National Water Quality Lab, USGS, Denver CO; and in USGS labs in Menlo Park, CA. One field visit on 8/20/2017 was made to obtain rock samples from the volcanic and sedimentary rocks in and around the park, which were digested and analyzed for whole rock chemistry...
Categories: Data;
Tags: Geochemistry,
Pinnacles National Park,
San Benito County,
Strontium isotopes,
USGS Science Data Catalog (SDC),
Ice core from Greenland was melted, filtered, and homogenized. Its stable hydrogen (δ2H) and oxygen (δ18O) isotopic compositions were adjusted to approximately match those of USGS46 ice core water (δ2H = –235.8 ‰ and δ18O = –29.80 ‰). This isotopic reference water, USGS46a, was loaded into glass ampules, sealed, autoclaved to eliminate biological activity, and calibrated by dual-inlet isotope-ratio mass spectrometry and laser absorption spectrometry. USGS46a is intended as one of two secondary isotopic reference waters for daily normalization of stable hydrogen and stable oxygen isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The measured δ2H and δ18O values of USGS46a reference...
Sediment composition data to support the manuscript "Multivariate analysis of shale gas development on the chemical and biological health of headwater streams".
This data release presents chemical and biological results from an investigation of the uptake of per- and polyfluoroalkyl substances (PFAS) from groundwater contaminated by fire training activities on Cape Cod, Massachusetts conducted from July to August 2019. An exposure experiment was conducted at an a PFAS contaminated site (FTA-1) near the fire training area (FTA). To assess the tissue-specific uptake characteristics of the mixture of PFAS present in the groundwater from the FTA-1 site, a 21-day mobile laboratory exposure experiment was conducted. Details for the groundwater sampling sites and well construction are presented (Table 1). The PFAS mixture concentrations and composition in groundwater and in fish...
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Biotic concentration,
Cape Cod,
Environmental Health,
Fathead minnows,
Fire training area,
The data presented here was collected at Prado Wetlands in Riverside County, CA, USA. Physical water column parameters were collected using a multprobe sonde and includes date and time of sample collection, location (inlet, outlet), temperature (degrees Celsius), pH, specific conductivity (mircoSiemens per centimeter), and dissolved oxygen (milligrams per liter). An ISCO autosampler was utilized to remotely collect diel water samples at the inlet and outlet of the wetland. These samples were analyzed for dissolved metals (aluminum, arsenic, boron, barium, beryllium, bismuth, bromine, calcium, cadmium, cerium, cobalt, chromium, copper, dysprosium, erbium, europium, iron, gallium, gadolinium, holmium, potassium, lanthanum,...
Categories: Data;
Tags: Prado Wetlands,
Riverside County,
Southern California,
USGS Science Data Catalog (SDC),
Water Quality,
Note: This data release has been deprecated. Please see new data release here: https://doi.org/10.5066/P9A4FVZ4. The data presented here was collected adjacent to USGS stream gage 06730200 and includes both observed and modeled values. Dissolved oxygen, dissolved carbon dioxide, stream depth, water temperature, and light intensity were collected via passive water quality sensors. Modeled values include gross primary production, ecosystem respiration, net ecosystem production, reaeration, and light (when observed values were unavailable). Modeled values were obtained through streamMetabolizer, a USGS-sponsored R-package for estimating rates of stream metabolism. Estimates for carbon dioxide flux utilized both modeled...
An international project developed, quality-tested, and measured isotope−delta values of 10 new food matrix reference materials (RMs) for hydrogen, carbon, nitrogen, oxygen, and sulfur stable isotope-ratio measurements to support food authenticity testing and food provenance verification. These new RMs, USGS82 to USGS91, will enable users to normalize measurements of samples to isotope−delta scales. The RMs include (i) two honeys, from Canada and tropical Vietnam, (ii) flours from C3 (rice) and C4 (millet) plants, (iii) four vegetable oils from C3 (olive, peanut) and C4 (corn) plants, and (iv) collagen powders from marine fish and terrestrial mammal origins.
Categories: Data;
Tags: USGS Science Data Catalog (SDC),
light stable isotope analysis,
materials standards
Surface sediment samples from the North San Francisco Bay-Delta Estuary were collected monthly at five stations located west of Rio Vista and east of Point Pinole. Sediment was collected near Montezuma Slough, Chips Island, the Concord Naval Weapons Station, Carquinez Strait near Martinez, and San Pablo Bay at water depths ranging from 6.5 to 14.3 meters. Samples were collected coincident with water-quality measurements (Cloern and Schraga, 2016) and metal concentrations in filter-feeding bivalves (Brown and Luoma, 1995; Stewart et al., 2013). Depending on the station, the period of record ranges from 13 to 24 years, from December 1993 to September 2017. Samples were sieved to <64 µm to eliminate grain-size bias...
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Carquinez Strait,
Metals,
San Francisco Bay Estuary,
San Pablo Bay,
Sediment Pollution,
This U.S. Geological Survey (USGS) Data Release is focused on the geochemistry of wastewater (including flowback and produced water) samples, co-produced with natural gas, collected from the Marcellus Shale Energy and Environment Laboratory (MSEEL) site. MSEEL is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The wells were completed in December 2015. Large volumes of wastewater are generated with natural gas production. These wastewaters...
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