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Temporal and spatial sources of silica for chert remain poorly constrained. Modern sources to the worlds oceans include silica in rivers > aeolian (dust) deposition > sea floor vents and submarine weathering. However, changes in aridity and dust flux during the Phanerozoic may explain variations in the ocean silica cycle and times and places of chert formation. The chemistry of fine quartz dust (FQD) provides a chemical mechanism for the transformation of FQD to polymorphs of silica in chert; FQD is readily dissolved, then reprecipitated as Opal-A by either biotic or abiotic processes. An unequivocal relation between increases in dust flux and biogenic opal-A in the western Pacific Ocean during the past 200 kyr...
The dataset consists of site identification, location, temperature and CO2 flux from diffuse emission measurement at the Tiptop fire. A total of 40 CO2 flux measurements were made at 27 locations, including five points (seven measurements) outside of the active coal fire area.
Categories: Data;
Tags: Energy Resources,
Environmental Health,
Kentucky,
Perry County,
USGS Science Data Catalog (SDC),
Solid organic matter (OM) in sedimentary rocks produces petroleum and solid bitumen when it undergoes thermal maturation. The solid OM is a 'geomacromolecule', usually representing a mixture of various organisms with distinct biogenic origins, and can have high heterogeneity in composition. Programmed pyrolysis is a common conventional method to reveal bulk geochemical characteristics of the dominant OM while detailed organic petrography is required to reveal information about the biogenic origin of contributing macerals. Despite advantages of programmed pyrolysis, it cannot provide information about the heterogeneity of chemical compositions present in the individual OM types. Therefore, other analytical techniques...
The dataset consists of geochemical and isotopic data from fine-grained sediments and glendonite crystals collected at Carter Creek on the North Slope of Alaska. Total Organic Carbon (TOC) values in the measured section were found to range between 0.5 and 3.5%, with a shift towards lower values in the uppermost 5 m of the section. Stable isotopes (13C) in organic matter were relatively stable throughout the section, ranging between -25.5 and -26, with a slight 0.3 per mil positive shift within this range approximately 57 m from the base of the section. Glendonites themselves were analyzed for δ13Ccarb and δ18Ocarb, with δ18O values relatively consistent between -0.22 and +1.28, and a much wider range of δ13C values...
This dataset includes ten years of emissions and sequestration estimates (2005-2014) in two separate tables, 1) the combustion and extraction of fossil fuels on Federal lands and 2) processes from the ecosystems on those Federal lands. The fossil fuel related estimates include the greenhouse gases carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O), and the ecosystems estimates include only CO2. The results are presented by State and year, including the Pacific and Gulf offshore areas in the fossil fuel associated estimates. In addition to total emissions, the estimates are broken into categories by the sector of the economy where the combustion or extraction related emissions occurred or the biologic process...
Categories: Data;
Tags: Climatology,
Energy Resources,
Environmental Health,
USGS Science Data Catalog (SDC),
United States of America,
High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter (SOM) is widely utilized in the geosciences for evaluation of microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM approaches, the inability of SEM to differentiate SOM types has hampered the pace of scientific advancement. In this study, we show that SEM-cathodoluminescence (CL) properties can be used to identify and characterize SOM at low thermal maturity conditions. Eleven varied mudstone samples with a broad array of SOM types, ranging from the Paleoproterozoic to...
Categories: Data;
Tags: Australia,
China,
Energy Resources,
Energy resources,
Fluorescence emission intensity,
The tables in this data release provide measures of quality for each of 304,643 records in the Mineral Resources Data System (MRDS) database, located at https://mrdata.usgs.gov/mrds/ describing mineral resources worldwide but focusing on those located in the United States. One table provides the measures of quality, the other provides the overall record scores that may be used to sort records by overall quality. MRDS is distributed from the U.S. Geological Survey (USGS) in several different formats for the convenience of a variety of different users. For example a flattened version of the database is available in which the one-to-many relationships in MRDS are suppressed by combining them into a single field, resulting...
Bravo Dome is a commercial natural CO2 field that supplies the gas to depleted oil fields for enhanced oil recovery. In order to understand the distribution of CO2 across the greater Bravo Dome region, including southeastern Colorado and northwestern New Mexico, and to assess the impacts of high CO2 concentrations on microbes in the subsurface, 7 samples were collected from sites associated with high natural CO2 concentrations. Four water samples were collected, two from wells producing within Bravo Dome, one from an oil and gas field north of Bravo Dome associated with high CO2 concentrations, the Oakdale field, and one sample from a shallow groundwater well on the Rafter K ranch that effervesces CO2. Three samples...
This study contains TOC and programmed pyrolysis data, as well as vitrinite reflectance collected from 12 samples taken from the Babouri-Figuil Sedimentary basin in northern Cameroon.
Categories: Data;
Tags: Babouri-Figuil Basin,
Cameroon,
Energy Resources,
Geochemistry,
USGS Science Data Catalog (SDC),
A U.S. Geological Survey (USGS) provisional geochemical and mineralogical database for hydrocarbon-rich shale in the Appalachian region has been compiled by Catherine Enomoto, Frank Dulong and Robert Milici for online distribution. USGS staff collaborated with geologists in State geological agencies to obtain samples that were analyzed for organic properties, including Rock Eval analyses, total organic carbon (TOC), thermal maturity, and semi-quantitative mineralogy. However, the database also contains previously published data, with appropriate citations included. Previously unpublished data are from samples collected and analyzed between 2007 and 2012 from wells drilled between 1931 and 2009, and from exposures...
Thirty-two organic-rich samples from the lower and upper shale members of the Devonian–Mississippian Bakken Formation were collected from eight cores across the Williston Basin, USA, at depths (~7,575–11,330 ft) representing immature through post peak oil/early condensate thermal maturity conditions. Reflectance results were correlated to programmed temperature pyrolysis parameters [hydrogen index (HI), production index (PI), Tmax], normal hydrocarbon and isoprenoid analysis of extractable organic matter (pristane/n-C17, phytane/n-C18) from GC analysis, and peak ratios from FTIR spectroscopy (branching ratio, A-factor).
Categories: Data;
Tags: Energy Resources,
Geochemistry,
North Dakota,
USGS Science Data Catalog (SDC),
geoscientificInformation,
Here the spatial variation in Raman estimates of thermal maturity within individual organic domains from several shale geologic reference materials originating from the Boquillas, Marcellus, Niobrara, and Woodford Formations are assessed from the respective Raman response. We show that for all four shales the thermal maturity parameters extracted from Raman spectra by iterative peak fitting can vary widely across distances of ≤5 µm within the same organic domain.
Categories: Data;
Tags: CEMEX quarry,
Carter County, Oklahoma,
Del Rio, Val Verde County, Texas,
Energy Resources,
Geochemistry,
Low biomass waters provide a unique challenge in the field of microbial ecology. It is difficult to determine, when biomass concentrations are extremely low, whether or not the sequencing data received are of good quality and representative of the waters sampled. Fifty-nine samples including 8 blanks were collected from a low biomass hydraulically fractured well producing from the Niobrara Shale in Colorado. At least 4 samples were collected by filtering the exact volume for each listed here: 1000 mL, 900 mL, 800 mL, 700 mL, 600 mL, 500 mL, 400 mL, 300 mL, 200 mL, 100 mL, 0 mL (blanks).
Categories: Data;
Tags: 16S rRNA sequencing,
Colorado,
Denver-Julesburg Basin,
Energy Resources,
Illumina MiSeq Platform,
Data on Produced Water Quality and Quantities from Hydraulically Fractured Williston Basin Oil Wells
This dataset contains compositional data on 17 produced water samples from hydraulically fractured unconventional oil wells completed in the Middle Bakken and Three Forks Formations. The oil wells are located in five different wellfields across the Williston Basin. Specific gravity, conductivity, temperature, pH and oxidation-reduction potential for each sample was measured in the field. Ions (B, Li, Cl, Na, Br), biomarkers (Pristane /n-C17 and Phytane /n-C18), glycol ether compounds, major ions, as well as radium (Ra-228/Ra-226), boron (δ11B), oxygen (δ18O) and hydrogen (δ2H) isotopic ratios were analyzed in the lab. Well profiles are provided to increase understanding of the produced waters compositions in the...
The U.S. Geological Survey assessed undiscovered petroleum resources in the downdip Paleogene formations of the U.S. Gulf Coast in 2018. During the assessment new data and information were collected to evaluate thermal maturity, source rock character, and unconventional reservoir rock prospectivity for the Cenozoic-aged section in south Louisiana. Samples were analyzed using multiple analytical approaches, including programmed pyrolysis (Rock-Eval), Leco TOC, organic petrographic analysis including vitrinite reflectance (Ro, %), and X-ray diffraction mineralogy. Associated abstract publication: Valentine, B.J., Elizalde, C., Enomoto, C.B., Hackley, P.C., 2015, Organic petrology and geochemistry of Tertiary and...
These geospatial data and their accompanying report outline many areas of coal in the United States beneath more than 3,000 ft of overburden. Based on depth, these areas may be targets for injection and storage of supercritical carbon dioxide. Additional areas where coal exists beneath more than 1,000 ft of overburden are also outlined; these may be targets for geologic storage of carbon dioxide in conjunction with enhanced coalbed methane production. These areas of deep coal were compiled as polygons into a shapefile for use in a geographic information system (GIS). The coal-bearing formation names, coal basin or field names, geographic provinces, coal ranks, coal geologic ages, and estimated individual coalbed...
This data release contains Rock-Eval pyrolysis, organic petrographic (reflectance), and X-ray diffraction mineralogy data for subsurface Mesozoic rock samples from the eastern onshore Gulf Coast Basin (primarily Mississippi and Louisiana). Samples were analyzed in support of the U.S. Geological Survey (USGS) assessment of undiscovered petroleum resources in the Upper Cretaceous Tuscaloosa marine shale and evaluation of shale gas prospectivity in the Aptian section of the Mississippi Salt Basin.
This data release consists of three products relating to a 82 x 50 neuron Emergent Self-Organizing Map (ESOM), which describes the multivariate topology of reservoir temperature and geochemical data for 190 samples of produced and geothermal waters from across the United States. Variables included in the ESOM are coordinates derived from reservoir temperature and concentration of Sc, Nd, Pr, Tb, Lu, Gd, Tm, Ce, Yb, Sm, Ho, Er, Eu, Dy, F, alkalinity as bicarbonate, Si, B, Br, Li, Ba, Sr, sulfate, H (derived from pH), K, Mg, Ca, Cl, and Na converted to units of proportion. The concentration data were converted to isometric log-ratio coordinates (following Hron et al., 2010), where the first ratio is Sc serving as...
Categories: Data;
Tags: Energy Resources,
USGS Science Data Catalog (SDC),
United States,
economic geology,
geochemistry,
The Midcontinent Rift System (MRS) of North America is one of the world’s largest continental rifts and has an age of 1.1 Ga (giga-annum). The MRS hosts a diverse suite of magmatic and hydrothermal mineral deposits in the Lake Superior region where rift rocks are exposed at or near the surface. As part of the construction of a database summarizing information on mineral deposits in the MRS, data from regional mineral deposits were downloaded from the U.S. Geological Survey (USGS) Mineral Resources Data System (MRDS), the USGS Mineral Deposit Database (USMIN), and the Ontario Ministry of Energy, Northern Development and Mines Mineral Deposit Inventory (MDI). Deposits related to MRS rocks or mineralizing events were...
The attached data are apatite and zircon fission track measurements from rock samples collected across the western Brooks Range. Table 1 contains descriptive information on each sample. Tables 2a, 2b, 2c, 2d and 2e contain single grain, apatite fission track age data for samples from each of five datasets that comprise the overall apatite fission track age dataset. Tables 3a, 3b, 3c, and 3d contain apatite fission track length data for samples from four of the five datasets that comprise the overall apatite fission track length dataset. The oldest of the five datasets has no accompanying track length data. Table 4 contains summary information for each of the apatite fission track age samples. Table 5 contains summary...
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